Functionalization of Polystyrene with Cyclic Anhydrides and Their Spectroscopic, Adhesive and Corrosive Characterizations
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Dosyalar
Tarih
2012
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Carl Hanser Verlag
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Polystyrene (PS) has been chemically modified with cyclic anhydrides such as glutaric anhydride (GA), citraconic anhydride (CA) and phthalic anhydride (PA) in the presence of BF3 center dot O(C2H5)(2) in chloroform and succinic anhydride (SA) in 1,2-dichloroethane. Some important reaction parameters were determined in order to optimize the acylation process. ATR FT-IR and H-1 NMR studies indicate that the acylation reaction can introduce both carboxyl group and double bond (for only citraconic anhydride) onto pendant aromatic groups of the polymer. The adhesion properties and corrosion resistance of the acylated PS on metal surface under various conditions have been investigated.
Açıklama
Anahtar Kelimeler
Kaynak
Internatıonal Polymer Processıng
WoS Q Değeri
Q3
Scopus Q Değeri
Q3
Cilt
27
Sayı
2
Künye
Önder, I. L., Okudan, A., (2012). Functionalization of Polystyrene with Cyclic Anhydrides and Their Spectroscopic, Adhesive and Corrosive Characterizations. Internatıonal Polymer Processıng, 27(2), 270-276. Doi: 10.3139/217.2536