1D Amorphous Tungsten-Based Ternary Refractory Metal Sulfides for Catalytic Hydrogen Evolution at Soft Interfaces

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dc.contributor.authorAslan, Emre
dc.contributor.authorSarilmaz, Adem
dc.contributor.authorOzel, Faruk
dc.contributor.authorPatir, Imren Hatay
dc.contributor.authorGirault, Hubert H.
dc.date.accessioned2020-03-26T20:12:13Z
dc.date.available2020-03-26T20:12:13Z
dc.date.issued2019
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractTransition metals incorporated into molybdenum sulfide and tungsten sulfide matrixes are promising candidates for hydrogen evolution due to the unique chemical and physical properties. Here, we first describe a general strategy for the synthesis of rod-like ternary refractory metal sulfides (MWSx; M=Ni, Co, Fe and Mn) through a simple hot-injection method. The newly developed materials are affirmed as valuable alternatives to noble metal Pt due to their simple fabrication, inexpensive and impressive catalytic performance. We present that highly efficient catalysts for the hydrogen evolution at a polarized water/1,2-dichloroethane (DCE) interface by using the decamethylferrocene (DMFc). Kinetics of hydrogen evolution studies are monitored by two phase reactions using UV/Vis spectroscopy, and also further proved by gas chromatography. These ternary refractory metal sulfide catalysts show high catalytic activities on hydrogen evolution comparable to platinum. The rate of hydrogen evolution for the MWSx catalysts changed in the order Ni>Co>Fe>Mn according to the type of first row transition metals.en_US
dc.description.sponsorshipTUBITAK (The Scientific and Technological Research Council of Turkey)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [215M309]; UNESCO-Loreal for Woman in Science program; Selcuk University Scientific Research ProjectsSelcuk University [17201020]; Turkish Academy of Sciences via a TUBA-GEBIPTurkish Academy of Sciencesen_US
dc.description.sponsorshipThe authors would like to thank TUBITAK (The Scientific and Technological Research Council of Turkey) (Grant number: 215M309), UNESCO-Loreal for Woman in Science program, Selcuk University Scientific Research Projects (Grant number: 17201020) and Turkish Academy of Sciences via a TUBA-GEBIP fellowship for supporting this work. This paper is the part of PhD thesis prepared by Emre Aslan.en_US
dc.identifier.doi10.1002/cnma.201900536en_US
dc.identifier.issn2199-692Xen_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://dx.doi.org/10.1002/cnma.201900536
dc.identifier.urihttps://hdl.handle.net/20.500.12395/37383
dc.identifier.wosWOS:000494843400001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWILEY-V C H VERLAG GMBHen_US
dc.relation.ispartofCHEMNANOMATen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjecthydrogen evolutionen_US
dc.subjectliquiden_US
dc.subjectliquid interfacesen_US
dc.subjectbiphasic reactionsen_US
dc.title1D Amorphous Tungsten-Based Ternary Refractory Metal Sulfides for Catalytic Hydrogen Evolution at Soft Interfacesen_US
dc.typeArticleen_US

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