The Interaction of Epoxy Toluene Oligomer Containing Chloromethyl Groups and P-Tert-Butylcalix[6]Arene

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dc.contributor.authorYıldız, S.
dc.contributor.authorVural, U. S.
dc.contributor.authorKurbanova, R.
dc.date.accessioned2020-03-26T16:24:35Z
dc.date.available2020-03-26T16:24:35Z
dc.date.issued1995
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractOligomeric toluene material which has epoxy group (ETO) was prepared through reaction of toluene and epichlorohidrine in the presence of BF3. Epoxy toluene oligomere containing chloromethyl groups (ETOC) was synthesized from the treatment of NaOH and ETO for 6-8 hours. The macromolecular derivative of oligomer, (ETOC-I-6) was obtained from the reaction of ETOC and p-tert-butylcalix[6]arene (I-6) in the presence of CH3ONa. When the concentration of ETOC is greater than I-6, the reaction was observed as pseudo first order, benzene was used as solvent. The activation energy and rate constant of the reaction were calculated as 25.082 kj . mol(-1) and 3.155.10(-5) s(-1), respectively. The amounts of chlorine in ETOC-I-6 was determined 6.37% by Schoniger Method, and its molecular weight was determined as 2778.84 g . mol(-1) by cryoscopic method using benzene as solvent.en_US
dc.identifier.citationYıldız, S., Vural, U. S., Kurbanova, R., (1995). The Interaction of Epoxy Toluene Oligomer Containing Chloromethyl Groups and P-Tert-Butylcalix[6]Arene. Journal of Macromolecular Science-Pure and Applied Chemistry, 32, 347-356.
dc.identifier.doi10.1080/10601329508019180en_US
dc.identifier.endpage356en_US
dc.identifier.issn1060-1325en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage347en_US
dc.identifier.urihttps://dx.doi.org/10.1080/10601329508019180
dc.identifier.urihttps://hdl.handle.net/20.500.12395/16307
dc.identifier.volumeA32en_US
dc.identifier.wosWOS:A1995QW11800013en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherMARCEL DEKKER INCen_US
dc.relation.ispartofJournal of Macromolecular Science-Pure and Applied Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.titleThe Interaction of Epoxy Toluene Oligomer Containing Chloromethyl Groups and P-Tert-Butylcalix[6]Areneen_US
dc.typeArticleen_US

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