The Synthesis and Characterization of s-Triazine-Cored Tripodal Structure and Its Salen/Salophen-Bridged Fe/Cr(III) Capped Complexes

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dc.contributor.authorKaratas, Erhan
dc.contributor.authorUcan, Halil Ismet
dc.date.accessioned2020-03-26T19:43:09Z
dc.date.available2020-03-26T19:43:09Z
dc.date.issued2017
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractA novel Schiff base compound was synthesized, and its complexation properties with Fe(III) and Cr(III) were investigated. Tripodal ligand was synthesized by the reaction of s-triazine and 4-hydroxybenzaldehyde. Then a Schiff base involving 8-hydroxyquinoline was synthesized by the reaction of 5-aminomethyl-8hydroxyquinoline (QN) and 2,4,6-tris(p-formylphenoxy)-1,3,5-triazine (TRIPOD) in methanol/chloroform media. The obtained Schiff base (QN-TRIPOD) was then reacted with four trinuclear Fe(III) and Cr(III) complexes including tetradentate Schiff bases N, N'-bis(salicylidene) ethylenediamine (salenH(2))/bis (salicylidene)-o-phenylenediamine (SalophenH(2)). The synthesized ligand and complexes were characterized by means of elemental analysis carrying out H-1 NMR, FTIR spectroscopy, thermal analyses, and magnetic susceptibility measurements. Finally, metal ratios of the prepared complexes were determined by using atomic adsorption spectrometry.en_US
dc.description.sponsorshipScientific Research Projects Foundation of Selcuk University (SUBAP)Selcuk University [2009/09101036]en_US
dc.description.sponsorshipWe thank the Scientific Research Projects Foundation of Selcuk University (SUBAP-Grant Number 2009/09101036) for financial support of this work produced from a part of Erhan Karatas's PhD Thesis.en_US
dc.identifier.doi10.1002/jhet.2642en_US
dc.identifier.endpage698en_US
dc.identifier.issn0022-152Xen_US
dc.identifier.issn1943-5193en_US
dc.identifier.issue1en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage692en_US
dc.identifier.urihttps://dx.doi.org/10.1002/jhet.2642
dc.identifier.urihttps://hdl.handle.net/20.500.12395/35614
dc.identifier.volume54en_US
dc.identifier.wosWOS:000394058900088en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWILEYen_US
dc.relation.ispartofJOURNAL OF HETEROCYCLIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.titleThe Synthesis and Characterization of s-Triazine-Cored Tripodal Structure and Its Salen/Salophen-Bridged Fe/Cr(III) Capped Complexesen_US
dc.typeArticleen_US

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