Synthesis of calix[4]arene mono and diamide derivatives and selective complexation of alkali and alkaline earth cations

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dc.contributor.authorBozkurt, Selahattin
dc.contributor.authorDurmaz, Mustafa
dc.contributor.authorSirit, Abdülkadir
dc.contributor.authorYılmaz, Mustafa
dc.date.accessioned2020-03-26T17:18:19Z
dc.date.available2020-03-26T17:18:19Z
dc.date.issued2007
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe synthesis of mono and diamide derivatives of the p-tert-butylcalix[4]arenes/calix[4]arenes from the reaction of 5,11,17,23-tetra-tert-butyl-25,27-diethoxycarbonyl-methoxy-26,28-dihydroxycalix[4]arene 1 and 25,27-diethoxycarbonyl-methoxy-26,28-dihydroxycalix[4] arene 2 with various primary amines were reported. The effect of reaction time and steric hindrance of the primary amines used on the reactions have been investigated. All the amide derivatives of calix[ 4] arene are in a cone conformation according to the H-1-NMR doublet-doublet pattern of the protons of the methylene groups between the aromatic rings. The complexing properties of these compounds toward selected alkali and alkaline earth metal cations are also studied. It has been observed that receptor 8 is a selective extractant for Cs+ and Sr2+ cations.en_US
dc.identifier.doi10.1080/10601320601030715en_US
dc.identifier.endpage165en_US
dc.identifier.issn1060-1325en_US
dc.identifier.issue2en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage159en_US
dc.identifier.urihttps://dx.doi.org/10.1080/10601320601030715
dc.identifier.urihttps://hdl.handle.net/20.500.12395/21637
dc.identifier.volume44en_US
dc.identifier.wosWOS:000243542100006en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTAYLOR & FRANCIS INCen_US
dc.relation.ispartofJOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectalkali and alkaline earth metal cationsen_US
dc.subjectdiamideen_US
dc.subjectcalix[4]areneen_US
dc.subjectmonoamideen_US
dc.subjectsolvent extractionen_US
dc.titleSynthesis of calix[4]arene mono and diamide derivatives and selective complexation of alkali and alkaline earth cationsen_US
dc.typeArticleen_US

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