Chiral calix[4]arenes bearing aminonaphthol moieties as membrane carriers for amino acid methyl esters and mandelic acid

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dc.contributor.authorDurmaz, Mustafa
dc.contributor.authorBozkurt, Selahattin
dc.contributor.authorNazıroğlu, Hayriye Nevin
dc.contributor.authorYılmaz, Mustafa
dc.contributor.authorSirit, Abdülkadir
dc.date.accessioned2020-03-26T18:13:55Z
dc.date.available2020-03-26T18:13:55Z
dc.date.issued2011
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractChiral calix[4]arene derivatives functionalized at the lower rim with chiral aminonaphthol units have been prepared. The structures of these receptors were characterized by a combination of (1)H NMR, (13)C NMR, FTIR and elemental analysis. The transport of amino acid derivatives (phenylglycine, phenylalanine and tryptophan methyl ester hydrochlorides) and mandelic acid were studied through a bulk liquid membrane in the presence of chiral calix[4]arene derivatives. The transport rate and enantioselectivity of the amino acid esters studied depended mainly upon the structure of the chiral receptors. The influence of calixarene and amino acid ester structures upon transport through a liquid membrane is discussed. The receptors with hydrogen bonding sites and aromatic groups showed considerable higher transport rates and stereoselectivities. (C) 2011 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipScientific and Technical Research Council of TurkeyTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TUBITAK-109T167]; Research Foundation of Selcuk UniversitySelcuk University [BAP-10101005]; TUBITAK-BIDEBTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK)en_US
dc.description.sponsorshipThis work was supported by the Scientific and Technical Research Council of Turkey (TUBITAK-109T167) and Research Foundation of Selcuk University (BAP-10101005). The provision of PhD studentship to M.D. by TUBITAK-BIDEB is gratefully acknowledged.en_US
dc.identifier.doi10.1016/j.tetasy.2011.04.019en_US
dc.identifier.endpage796en_US
dc.identifier.issn0957-4166en_US
dc.identifier.issue7en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage791en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.tetasy.2011.04.019
dc.identifier.urihttps://hdl.handle.net/20.500.12395/26228
dc.identifier.volume22en_US
dc.identifier.wosWOS:000292679700013en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPERGAMON-ELSEVIER SCIENCE LTDen_US
dc.relation.ispartofTETRAHEDRON-ASYMMETRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.titleChiral calix[4]arenes bearing aminonaphthol moieties as membrane carriers for amino acid methyl esters and mandelic aciden_US
dc.typeArticleen_US

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