The Synthesis and Ni(Ii), Co(Ii), Cu(Ii), Zn(Ii), Cd(Ii) and Uo2(Vi) Complexes of N,N'-Bis(2-tolyl)Diaminoglyoxime and N,N'-Bis(4-tolyl)Diaminoglyoxime

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dc.contributor.authorMercimek, Bedrettin
dc.contributor.authorÖzcan, Emine
dc.contributor.authorPekacar, All İhsan
dc.date.accessioned2020-03-26T16:24:35Z
dc.date.available2020-03-26T16:24:35Z
dc.date.issued1995
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractN,N'-Bis(2-toyl)diaminoglyoxime (L(1)H(2)) and N,N'-bis(4-tolyl)diaminoglyoxime (L(2)H(2)) have been prepared from anti-dichloroglyoxime with o-toluidine and p-toluidine in ethanol. The complexes of these vic-dioximes with Ni(II), Co(II), Cu(II), Zn(II), Cd(II) and UO2(VI) metal ions have been investigated. The nickel(II), cobalt(ll) and copper(ll) complexes of the ligands have a metal-ligand ratio of 1:2 and the ligand oo-ordinates through the N atoms, as do most of the vic-dioximes. [Zn(LH)Cl(O-2)] and [Cd(LH)CI(H2O)] (LH(2) = L(1)H(2) or L(2)H(2)) form six-membered chelate rings and co-ordinate through N and O atoms. LH(2) reacts with UO2(CH3COO)(2) . 2H(2)O to give binuclear complexes with a metal-ligand ratio of 1:1. Their structures were identified by elemental analyses and H-1 NMR, IR, UV-visible spectroscopy, respectively.en_US
dc.identifier.citationMercimek, B., Özcan, E., Pekacar, A. İ., (1995). The Synthesis and Ni(Ii), Co(Ii), Cu(Ii), Zn(Ii), Cd(Ii) and Uo2(Vi) Complexes of N,N'-Bis(2-tolyl)Diaminoglyoxime and N,N'-Bis(4-tolyl)Diaminoglyoxime. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 25(9), 1571-1579. DOI:10.1080/15533179508218291
dc.identifier.doi10.1080/15533179508218291en_US
dc.identifier.endpage1579en_US
dc.identifier.issn0094-5714en_US
dc.identifier.issue9en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage1571en_US
dc.identifier.urihttps://dx.doi.org/10.1080/15533179508218291
dc.identifier.urihttps://hdl.handle.net/20.500.12395/16311
dc.identifier.volume25en_US
dc.identifier.wosWOS:A1995TA83700013en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorMercimek, Bedrettin
dc.institutionauthorÖzcan, Emine
dc.institutionauthorPekacar, All İhsan
dc.language.isoenen_US
dc.publisherMARCEL DEKKER INCen_US
dc.relation.ispartofSynthesis and Reactivity in Inorganic and Metal-Organic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.titleThe Synthesis and Ni(Ii), Co(Ii), Cu(Ii), Zn(Ii), Cd(Ii) and Uo2(Vi) Complexes of N,N'-Bis(2-tolyl)Diaminoglyoxime and N,N'-Bis(4-tolyl)Diaminoglyoximeen_US
dc.typeArticleen_US

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