Study on the Second Order Optical Properties of N-(2,4-dichloro)-salicylaldimine

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dc.contributor.authorKarakaş, Aslı
dc.contributor.authorÜnver, Hüseyin
dc.contributor.authorElmalı, Ayhan
dc.contributor.authorSvoboda, Ingrid
dc.date.accessioned2020-03-26T16:58:57Z
dc.date.available2020-03-26T16:58:57Z
dc.date.issued2005
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractN-(2,4-Dichloro)-salicylaldimine was synthesized, characterized by elemental analysis, FT-IR, and UV-visible spectroscopy, and its crystal structure was determined. The title compound is almost planar and contains short intramolecular O-H... N hydrogen bonds [O1-N1 2.601(1) Å]. It remains transparent in the visible region and has solvatochromic behavior in the UV region in the range 198 349 nm, implying non-zero microscopic first hyperpolarizability. The ab-initio quantum mechanical calculations (finite field second-order Møller Plesset perturbation theory) of the studied compound have been carried out to compute the electric dipole moment (?) and the first hyperpolarizability (?) values. The ab-initio results also show that this ligand might have microscopic nonlinear optical behavior with non-zero values.en_US
dc.description.sponsorshipAnkara Universitesi: 2003/030, CHE 2003 00 00 041en_US
dc.description.sponsorshipThe authors wish to acknowledge that this work was supported by the Research Funds of Selc¸uk University and Ankara University under grant numbers 2003/030 and CHE 2003 00 00 041, respectively.en_US
dc.identifier.citationKarakaş, A., Ünver, H., Elmali, A., Svoboda, I., (2005). Study on the Second Order Optical Properties of N-(2, 4-dichloro)-salicylaldimine. Verlag der Zeitschrift fur Naturforschung, 60(5), 376-382.
dc.identifier.doi10.1515/zna-2005-0510en_US
dc.identifier.endpage382en_US
dc.identifier.issn0932-0784en_US
dc.identifier.issue5en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage376en_US
dc.identifier.urihttps://dx.doi.org/10.1515/zna-2005-0510
dc.identifier.urihttps://hdl.handle.net/20.500.12395/20043
dc.identifier.volume60en_US
dc.identifier.wosWOS:000229779400010en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorKarakaş, Aslı
dc.language.isoenen_US
dc.publisherVerlag der Zeitschrift fur Naturforschungen_US
dc.relation.ispartofZeitschrift fur Naturforschung - Section A Journal of Physical Sciencesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectAb-initio Calculationen_US
dc.subjectCrystal Structureen_US
dc.subjectFirst Hyperpolarizabilityen_US
dc.subjectNonlinear Opticsen_US
dc.subjectUv-visible Spectroscopyen_US
dc.titleStudy on the Second Order Optical Properties of N-(2,4-dichloro)-salicylaldimineen_US
dc.typeArticleen_US

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