Thiol-ene-clickable and emissive carbazole-based polymer networks with tunable colors

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dc.contributor.authorDoyranli, Ceylan
dc.contributor.authorBuyukcelebi, Sumeyra
dc.contributor.authorKoyuncu, Sermet
dc.contributor.authorUsluer, Ozlem
dc.contributor.authorKus, Mahmut
dc.contributor.authorKoyuncu, Fatma Baycan
dc.date.accessioned2020-03-26T19:31:45Z
dc.date.available2020-03-26T19:31:45Z
dc.date.issued2016
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractBand gap tuning and processability of organic materials are significant topics for both scientific research and commercial applications. In this study, we synthesized a series of main chain cross-linkable polymers by thiol-ene click chemistry from N-allyl carbazole and different heterocycles via conventional Suzuki coupling polymerization reaction. The emission color of polymers could be successfully tuned from blue to red by attaching different benzazole-acceptor moieties to the carbazole donor unit. We also investigated the effects of cross-linking with respect to the amount of pentaerythritol tetrakis(3-mercaptopropionate) cross-linker on the optical, electrochemical, and surface morphological properties of the polymer films. The results showed that these polymers can be used as emissive active layers in solution-processable multilayer organic light-emitting diodes. (C) 2016 Published by Elsevier B.V.en_US
dc.description.sponsorshipScientific and Technical Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [113Z255]en_US
dc.description.sponsorshipThe authors would like to thank the Scientific and Technical Research Council of Turkey (TUBITAK) for financial support (Project number: 113Z255).en_US
dc.identifier.doi10.1016/j.reactfunctpolym.2016.07.003en_US
dc.identifier.endpage23en_US
dc.identifier.issn1381-5148en_US
dc.identifier.issn1873-166Xen_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage17en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.reactfunctpolym.2016.07.003
dc.identifier.urihttps://hdl.handle.net/20.500.12395/34144
dc.identifier.volume106en_US
dc.identifier.wosWOS:000382803200003en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE BVen_US
dc.relation.ispartofREACTIVE & FUNCTIONAL POLYMERSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectThiol-ene click reactionen_US
dc.subjectCross-linkable polymersen_US
dc.subjectTunable colorsen_US
dc.subjectCarbazoleen_US
dc.subjectEmissive polymersen_US
dc.titleThiol-ene-clickable and emissive carbazole-based polymer networks with tunable colorsen_US
dc.typeArticleen_US

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