Facilitated Proton Transfer by a Novel 2-Aminothiazole Derivative Across the Water/1,2-Dichloroethane Interface

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dc.contributor.authorBingol, Haluk
dc.contributor.authorCoskun, Ahmet
dc.date.accessioned2020-03-26T18:14:39Z
dc.date.available2020-03-26T18:14:39Z
dc.date.issued2011
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe behavior of proton transfer facilitated by a novel thiazole derivative, N-methyl-4-(4-phenoxyphenyl)thiazol-2-amine (MPPT), across the water/1,2-dichloroethane (1,2-DCE) interface was investigated electrochemically. The ionic partition diagram for MPPT was obtained from interpretation of the cyclic voltammograms. The apparent partition coefficient of MPPT was evaluated by the shaking-flask method under experimental conditions, while that for the protonated form of MPPT was calculated from its transfer potential obtained from the ionic partition diagram. It was suggested that the mechanism for transfer of MPPT across the water/1,2-DCE) interface depends on the pH of the aqueous phase. The parameters of the facilitated proton transfer across the water/1,2-DCE interface were evaluated as a quantitative measure of its lipophilicity.en_US
dc.identifier.doi10.1007/s10953-011-9681-7en_US
dc.identifier.endpage1515en_US
dc.identifier.issn0095-9782en_US
dc.identifier.issn1572-8927en_US
dc.identifier.issue8en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage1505en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10953-011-9681-7
dc.identifier.urihttps://hdl.handle.net/20.500.12395/26491
dc.identifier.volume40en_US
dc.identifier.wosWOS:000294354400010en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSPRINGER/PLENUM PUBLISHERSen_US
dc.relation.ispartofJOURNAL OF SOLUTION CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectProton transferen_US
dc.subjectThiazoleen_US
dc.subjectITIESen_US
dc.subjectIonic partition diagramen_US
dc.subjectCyclic voltammetryen_US
dc.subjectLipophilicityen_US
dc.titleFacilitated Proton Transfer by a Novel 2-Aminothiazole Derivative Across the Water/1,2-Dichloroethane Interfaceen_US
dc.typeArticleen_US

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