Enhanced Hydrogen Evolution Catalysis at the Liquid/Liquid Interface by NixSy and NixSy/Carbon Nanotube Catalysts

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dc.contributor.authorAkin, Ilker
dc.contributor.authorAslan, Emre
dc.contributor.authorPatir, Imren Hatay
dc.date.accessioned2020-03-26T19:41:42Z
dc.date.available2020-03-26T19:41:42Z
dc.date.issued2017
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractNixSy (NiS and Ni17S18) nanoparticles and their nano-composite with carbon nanotubes (NixSy/CNT) were synthesized by a modified hydrothermal method and characterized by X-ray diffraction, Raman spectroscopy, scanning electron microscopy, and energy-dispersive X-ray microanalysis. The synthesized materials were used as hydrogen evolution catalysts at the water/1,2-dichloroethane interface by using decamethylferrocene as a lipophilic electron donor. The hydrogen evolution reaction in biphasic systems was investigated by two-phase reactions and by cyclic voltammetry with a four-electrode system. A kinetic study of the hydrogen production was also performed. The rates of the reactions catalyzed by the NixSy nanoparticles and the NixSy/CNT nanocomposite were found to be about 690-fold and 2000-fold higher, respectively, than the rate for the reaction performed in the absence of a catalyst.en_US
dc.description.sponsorshipSelcuk University Scientific Research Projects (BAP)Selcuk University [15401115]; Scientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [215M309]; Turkish Academy of Sciences via a TUBA-GEBIP fellowshipen_US
dc.description.sponsorshipThe authors would like to thank the Selcuk University Scientific Research Projects (BAP, 15401115) and The Scientific and Technological Research Council of Turkey (TUBITAK) (215M309) for supporting this work. We also gratefully acknowledge the research support of the Turkish Academy of Sciences via a TUBA-GEBIP fellowship.en_US
dc.identifier.doi10.1002/ejic.201700873en_US
dc.identifier.endpage3966en_US
dc.identifier.issn1434-1948en_US
dc.identifier.issn1099-0682en_US
dc.identifier.issue33en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage3961en_US
dc.identifier.urihttps://dx.doi.org/10.1002/ejic.201700873
dc.identifier.urihttps://hdl.handle.net/20.500.12395/35072
dc.identifier.wosWOS:000409522600014en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWILEY-V C H VERLAG GMBHen_US
dc.relation.ispartofEUROPEAN JOURNAL OF INORGANIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectHydrogenen_US
dc.subjectNanotubesen_US
dc.subjectNanoparticlesen_US
dc.subjectNickelen_US
dc.subjectInterfacesen_US
dc.titleEnhanced Hydrogen Evolution Catalysis at the Liquid/Liquid Interface by NixSy and NixSy/Carbon Nanotube Catalystsen_US
dc.typeArticleen_US

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