Improving the performance of inverted polymer solar cells through modification of compact TiO2 layer by different boronic acid functionalized self-assembled monolayers

dc.contributor.authorKırbıyık, Çisem.
dc.contributor.authorKara, Duygu Akın.
dc.contributor.authorKara, Koray.
dc.contributor.authorBüyükçelebi, Sümeyra.
dc.contributor.authorYiğit, Mesude Zeliha.
dc.contributor.authorCan, Mustafa.
dc.contributor.authorKuş, Mahmut.
dc.date.accessioned2020-03-26T20:14:38Z
dc.date.available2020-03-26T20:14:38Z
dc.date.issued2019
dc.departmentSelçuk Üniversitesi, Mühendislik Fakültesi, Kimya Mühendisliği Bölümüen_US
dc.description.abstractIn this study, we demonstrate the use of a series of boronic acid functionalized self-assembled monolayers (SAMs) to improve photovoltaic device performance P3HT and PCBM based solar cells. The SAMs treated compact TiO2 (c-TiO2) layer was utilized as an electron transport layer for inverted polymer solar cells (PSCs) with a configuration of FTO/c-TiO2/SAM/P3HT:PCBM/PEDOT:PSS/Ag. The modified with 3,4,5-methoxyphenylboronic acid (3-OMe) SAM shows the best improving due to the enhancement of J(sc) and V-oc. in device, which leads to a 26% improvement (2.8%) over non-modified device (2.2%). The enhancement in the modified devices is achieved by SAM modification reducing recombination of charges and improving charge selectivity. These results prove that the surface and electrical properties of compact TiO2 (c-TiO2) layer can be easily tuned as well as the upper layer morphology can be controlled by SAM modification.en_US
dc.identifier.citationKırbıyık, Ç., Kara, D. A., Kara, K., Büyükçelebi, S., Yiğit, M. Z., Can, M., Kuş, M. (2019). Improving the Performance of Inverted Polymer Solar Cells Through Modification of Compact TiO2 Layer by Different Boronic Acid Functionalized Self-Assembled Monolayers. Applied Surface Science, 479, 177-184.
dc.identifier.doi10.1016/j.apsusc.2019.01.268en_US
dc.identifier.endpage184en_US
dc.identifier.issn0169-4332en_US
dc.identifier.issn1873-5584en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage177en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.apsusc.2019.01.268
dc.identifier.urihttps://hdl.handle.net/20.500.12395/37911
dc.identifier.volume479en_US
dc.identifier.wosWOS:000464931800022en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorKırbıyık, Çisem.
dc.institutionauthorKara, Koray.
dc.institutionauthorBüyükçelebi, Sümeyra.
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE BVen_US
dc.relation.ispartofAPPLIED SURFACE SCIENCEen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectSelf-assembled monolayeren_US
dc.subjectBulk heterojunctionen_US
dc.subjectPolymer solar cellsen_US
dc.subjectCompact TiO2en_US
dc.titleImproving the performance of inverted polymer solar cells through modification of compact TiO2 layer by different boronic acid functionalized self-assembled monolayersen_US
dc.typeArticleen_US

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