The Synthesis and Characterization of Melamine Based and [Fe/CrSalen] or [Fe/CrSalophen] Capped Polimer Schiff Base Complexes
Küçük Resim Yok
Tarih
2010
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
SPRINGER
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In this study, by using previously reported monomer complexes [(2-(4-carboxybenzimino)-4,6-diamino-1,3,5-triazine)(salen/salophenFeIII)], [(2-(4-carboxybenzimino)-4,6-diamino-1,3,5-triazine)(salen/salophenCrIII)], [(2-(3,4-dihydroxybenzimino)-4,6-diamino-1,3,5-triazine)(salen/salophenFeIII)] and [(2-(3,4-dihydroxybenzimino)-4,6-diamino-1,3,5-triazine)(salen/salophenCrIII)] obtained by Uysal and U double dagger an (J Inc Phenom Macrocycl Chem, in press), sixteen new polimer Fe(III) and Cr(III) complexes involving tetradentate Schiff bases N,N'-bis (salicylidene)ethylenediamine-(salenH(2)) or bis(salicylidene)-o-phenylenediamine-(salophenH(2)) with 2-(4-carboxybenzimino)-4,6-diamino-1,3,5-triazine or 2-(3,4-dihydroxybenzimino)-4,6-diamino-1,3,5-triazine (Uysal and U double dagger an, J Inc Phenom Macrocycl Chem, in press) and terephthaldehyde or glutaraldehyde have been synthesized and characterized by means of elemental analysis, H-1 N.M.R., FT-IR spectrscopy, MS, thermal analyses and magnetic susceptibility measurements. The complexes have also been characterized as low-spin distorted octahedral Fe(III) and Cr(III) bridged by catechol and/or COO- groups.
Açıklama
Anahtar Kelimeler
Melamine, Salen, Salophen, Schiff bases, Co-polymers, Polymer complexes
Kaynak
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
20
Sayı
4
