The synthesis and characterization of single substitute melamine cored Schiff bases and their [Fe(III) and Cr(III)] complexes
dc.contributor.author | Uysal, Saban | |
dc.contributor.author | Ucan, H. Ismet | |
dc.date.accessioned | 2020-03-26T18:05:24Z | |
dc.date.available | 2020-03-26T18:05:24Z | |
dc.date.issued | 2010 | |
dc.department | Selçuk Üniversitesi | en_US |
dc.description.abstract | In this study, firstly, two single substitute novel ligands have been synthesized by reacting melamine with 3,4,-dihydroxybenzaldeyhde or 4-carboxybenzaldehyde. Then, eight new mono nuclear single substitute [Salen/Salophen Fe(III) and Cr(III)] complexes have been synthesized by reacting the ligands [2-(3,4-dihydroxybenzimino)-4,6-diamimo-1,3,5-triazine and 2-(4-carboxybenzimino)-4,6-diamimo-1,3,5-triazine)] with tetradentate Schiff bases N,N'-bis(salicylidene)ethylenediamine-(salenH(2)) or bis(salicylidene)-o-phenylenediamine-(salophen H-2). And then, all ligands and complexes have been characterized by means of elementel analysis, FT-IR spectroscopy, H-1 NMR, LC-MS, thermal analyses and magnetic suscebtibility measurements. Finally, metal ratios of the prepared complexes were determined using AAS. The complexes have also been characterized as disorted octahedral low-spin Fe(III) and Cr(III) bridged by catechol and COO- groups. | en_US |
dc.description.sponsorship | Selcuk UniversitySelcuk University [2005/5201005] | en_US |
dc.description.sponsorship | The authors would like to acknowledge the Scientific Research Projects (BAP) of Selcuk University for supporting this study through a grant: 2005/5201005. | en_US |
dc.identifier.doi | 10.1007/s10847-010-9762-z | en_US |
dc.identifier.endpage | 173 | en_US |
dc.identifier.issn | 1388-3127 | en_US |
dc.identifier.issn | 1573-1111 | en_US |
dc.identifier.issue | 01.02.2020 | en_US |
dc.identifier.scopusquality | Q3 | en_US |
dc.identifier.startpage | 165 | en_US |
dc.identifier.uri | https://dx.doi.org/10.1007/s10847-010-9762-z | |
dc.identifier.uri | https://hdl.handle.net/20.500.12395/25414 | |
dc.identifier.volume | 68 | en_US |
dc.identifier.wos | WOS:000281702800017 | en_US |
dc.identifier.wosquality | Q2 | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.publisher | SPRINGER | en_US |
dc.relation.ispartof | JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.selcuk | 20240510_oaig | en_US |
dc.subject | Melamine | en_US |
dc.subject | Salen | en_US |
dc.subject | Salophen | en_US |
dc.subject | Schiff bases | en_US |
dc.subject | Catechol | en_US |
dc.title | The synthesis and characterization of single substitute melamine cored Schiff bases and their [Fe(III) and Cr(III)] complexes | en_US |
dc.type | Article | en_US |