The synthesis and characterization of single substitute melamine cored Schiff bases and their [Fe(III) and Cr(III)] complexes

dc.contributor.authorUysal, Saban
dc.contributor.authorUcan, H. Ismet
dc.date.accessioned2020-03-26T18:05:24Z
dc.date.available2020-03-26T18:05:24Z
dc.date.issued2010
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractIn this study, firstly, two single substitute novel ligands have been synthesized by reacting melamine with 3,4,-dihydroxybenzaldeyhde or 4-carboxybenzaldehyde. Then, eight new mono nuclear single substitute [Salen/Salophen Fe(III) and Cr(III)] complexes have been synthesized by reacting the ligands [2-(3,4-dihydroxybenzimino)-4,6-diamimo-1,3,5-triazine and 2-(4-carboxybenzimino)-4,6-diamimo-1,3,5-triazine)] with tetradentate Schiff bases N,N'-bis(salicylidene)ethylenediamine-(salenH(2)) or bis(salicylidene)-o-phenylenediamine-(salophen H-2). And then, all ligands and complexes have been characterized by means of elementel analysis, FT-IR spectroscopy, H-1 NMR, LC-MS, thermal analyses and magnetic suscebtibility measurements. Finally, metal ratios of the prepared complexes were determined using AAS. The complexes have also been characterized as disorted octahedral low-spin Fe(III) and Cr(III) bridged by catechol and COO- groups.en_US
dc.description.sponsorshipSelcuk UniversitySelcuk University [2005/5201005]en_US
dc.description.sponsorshipThe authors would like to acknowledge the Scientific Research Projects (BAP) of Selcuk University for supporting this study through a grant: 2005/5201005.en_US
dc.identifier.doi10.1007/s10847-010-9762-zen_US
dc.identifier.endpage173en_US
dc.identifier.issn1388-3127en_US
dc.identifier.issn1573-1111en_US
dc.identifier.issue01.02.2020en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage165en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10847-010-9762-z
dc.identifier.urihttps://hdl.handle.net/20.500.12395/25414
dc.identifier.volume68en_US
dc.identifier.wosWOS:000281702800017en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectMelamineen_US
dc.subjectSalenen_US
dc.subjectSalophenen_US
dc.subjectSchiff basesen_US
dc.subjectCatecholen_US
dc.titleThe synthesis and characterization of single substitute melamine cored Schiff bases and their [Fe(III) and Cr(III)] complexesen_US
dc.typeArticleen_US

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