Synthesis of a novel calix[4]azacrown ionophore and its extraction ability toward Cr(VI)

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dc.contributor.authorÖzcan, Fatih
dc.contributor.authorMalkondu, Sait
dc.contributor.authorKoçak, Ahmet
dc.contributor.authorKoçak, Nuriye
dc.contributor.authorYılmaz, Mustafa
dc.date.accessioned2020-03-26T18:43:39Z
dc.date.available2020-03-26T18:43:39Z
dc.date.issued2013
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe present study describes the synthesis of a novel extractant p-tert-butyl-calix[4]azacrown ionophore (5) and evaluation of its extraction capability toward dichromate ion from aqueous solution. At first, p-tert-butyl-calix[4]azacrown ionophore (5) has been synthesized from the condensation of p-tert-butyl-calix[4]arene diamine (3) with N-(4-formylphenyl)-aza-15-crown-5 (4). The studies regarding the removal of dichromate ion from the aqueous solutions have been carried out in the liquid-liquid extraction systems. The extraction results showed that p-tert-butyl-calix[4]azacrown derivative (5) exhibited generally higher affinity towards dichromate ion than both 3 and 4 at all studied pHs.en_US
dc.description.sponsorshipSU Research FoundationSelcuk Universityen_US
dc.description.sponsorshipThe authors gratefully acknowledge financial support from SU Research Foundation.en_US
dc.identifier.doi10.1007/s10847-012-0215-8en_US
dc.identifier.endpage449en_US
dc.identifier.issn1388-3127en_US
dc.identifier.issn1573-1111en_US
dc.identifier.issue03.04.2020en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage443en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10847-012-0215-8
dc.identifier.urihttps://hdl.handle.net/20.500.12395/29867
dc.identifier.volume76en_US
dc.identifier.wosWOS:000323910900022en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCalixazacrownen_US
dc.subjectDichromate anionen_US
dc.subjectLiquid-liquid extractionen_US
dc.titleSynthesis of a novel calix[4]azacrown ionophore and its extraction ability toward Cr(VI)en_US
dc.typeArticleen_US

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