Novel Water-Soluble Calix[4,6]arene Appended Magnetic Nanoparticles for the Removal of the Carcinogenic Aromatic Amines

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dc.contributor.authorAksoy, Tuba
dc.contributor.authorErdemir, Serkan
dc.contributor.authorYıldız, H. Bekir
dc.contributor.authorYılmaz, Mustafa
dc.date.accessioned2020-03-26T18:30:56Z
dc.date.available2020-03-26T18:30:56Z
dc.date.issued2012
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThis article describes the synthesis of p-sulfonated calix[4,6]arene derivatives and firstly their immobilization onto magnetic nanoparticles for removal of some carcinogenic aromatic amines. The prepared new water-soluble calix[4,6]arene appended magnetic nanoparticles (p-C[4]-MN and p-C[6]-MN) were characterized by a combination of Fourier transform infrared spectroscopy, scanning electron microscopy, and thermogravimetric analyses. The separation and quantification of aromatic amines were performed by high performance liquid chromatography. In batch sorption experiments, the compounds 7 and 8 were found to be effective sorbent for aromatic amines. It was observed that the percentage of aromatic amine removal was 44-97 % for compound 7 and 63-97 % for 8 when the pH of the aromatic amine solution was in the range of 3.0-8.5. The sorption of aromatic amines by p-sulfonated calix[n]arenes-based magnetic nanoparticles shows that sulfonic acid groups play a major role for the formation of hydrogen bonds and electrostatic interactions.en_US
dc.description.sponsorshipScientific Research Projects Foundation of Selcuk University (SUBAP)Selcuk University [2010-10201075]en_US
dc.description.sponsorshipWe thank the Scientific Research Projects Foundation of Selcuk University (SUBAP Grant Number 2010-10201075) for the financial support of this work.en_US
dc.identifier.citationAksoy, T., Erdemir, S., Yıldız, H. B., Yılmaz, M., (2012). Novel Water-Soluble Calix[4,6]arene Appended Magnetic Nanoparticles for the Removal of the Carcinogenic Aromatic Amines. Water Air and Soil Pollution, 223(7), 4129-4139. Doi 10.1007/s11270-012-1179-4
dc.identifier.doi10.1007/s11270-012-1179-4en_US
dc.identifier.endpage4139en_US
dc.identifier.issn0049-6979en_US
dc.identifier.issue7en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage4129en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s11270-012-1179-4
dc.identifier.urihttps://hdl.handle.net/20.500.12395/28262
dc.identifier.volume223en_US
dc.identifier.wosWOS:000307276400045en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorAksoy, Tuba
dc.institutionauthorErdemir, Serkan
dc.institutionauthorYılmaz, Mustafa
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofWater Air and Soil Pollutionen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCalixareneen_US
dc.subjectNanoparticleen_US
dc.subjectAromatic aminesen_US
dc.subjectSorptionen_US
dc.subjectHPLCen_US
dc.titleNovel Water-Soluble Calix[4,6]arene Appended Magnetic Nanoparticles for the Removal of the Carcinogenic Aromatic Aminesen_US
dc.typeArticleen_US

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