The Synthesis and Ni(Ii), Co(Ii), Cu(Ii), Zn(Ii), Cd(Ii) and Hg(Ii) Complexes of Bis(Delta(2)-2-Pyrimidinyl)-6,6'-Dioxime Dihydrochloride

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dc.contributor.authorMercimek,Bedrettin
dc.contributor.authorIrez,Gazi
dc.date.accessioned2020-03-26T16:24:35Z
dc.date.available2020-03-26T16:24:35Z
dc.date.issued1995
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractIn this work, bis(Delta(2)-2-pyrimidinyl)-6,6-dioxime dihydrochloride (H(2)L . 2HCl) was synthesized by reacting anti-dichloroglyoxime with bis(Delta(2)-2-pyrimidinyl) (L) and complexes of the resulting vic-dioxime with Ni(II), Co(II), Cd(II) and Hg(II) were prepared. The Ni(II) and Co(II) complexes with a metal-ligand ratio 1:2 possess the mononuclear structure [M(HL)(2)] {M = Ni(II) or Co(II)}, white that of Cu(II) with a metal-ligand ratio of 3:2 possesses the trinuclear structure [Cu-3(HL)(2)Cl-4]. The Zn(II), Cd(II) and Hg(II) complexes of H(2)L have a metal-ligand ratio of 1:1 and [(HL)Cl(H2O)M] contains six-membered chelate rings. The reaction of mononuclear complexes of Ni(II) or Co(II) with Cu(lt) gives heterotrinuclear complexes [M M'(2)(HL)(2)Cl-4] {M = Ni(II) or Co(II) and M' - Cu(II)}. The structures of these complexes are proposed based on elemental analyses, i.r., and magnetic susceptibility measurements.en_US
dc.identifier.citationMercimek, B., Irez, G., (1995). The Synthesis and Ni(Ii), Co(Ii), Cu(Ii), Zn(Ii), Cd(Ii) and Hg(Ii) Complexes of Bis(Delta(2)-2-Pyrimidinyl)-6,6'-Dioxime Dihydrochloride. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 25(3). 337-347. DOI:10.1080/15533179508218224
dc.identifier.doi10.1080/15533179508218224en_US
dc.identifier.endpage347en_US
dc.identifier.issn0094-5714en_US
dc.identifier.issue3en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage337en_US
dc.identifier.urihttps://dx.doi.org/10.1080/15533179508218224
dc.identifier.urihttps://hdl.handle.net/20.500.12395/16310
dc.identifier.volume25en_US
dc.identifier.wosWOS:A1995QT23800001en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorMercimek,Bedrettin
dc.institutionauthorIrez,Gazi
dc.language.isoenen_US
dc.publisherMARCEL DEKKER INCen_US
dc.relation.ispartofSynthesis and Reactivity in Inorganic and Metal-Organic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.titleThe Synthesis and Ni(Ii), Co(Ii), Cu(Ii), Zn(Ii), Cd(Ii) and Hg(Ii) Complexes of Bis(Delta(2)-2-Pyrimidinyl)-6,6'-Dioxime Dihydrochlorideen_US
dc.typeArticleen_US

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