Initiated CVD of Tertiary Amine-Containing Glycidyl Methacrylate Copolymer Thin Films for Low Temperature Aqueous Chemical Functionalization

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dc.contributor.authorSariipek, Fatma
dc.contributor.authorKaraman, Mustafa
dc.date.accessioned2020-03-26T18:51:10Z
dc.date.available2020-03-26T18:51:10Z
dc.date.issued2014
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThis manuscript reports on the synthesis of copolymer films of glycidyl methacrylate with diethylaminoethyl methacrylate by initiated (i)CVD. The purpose of the incorporation of tertiary amine functionality in the copolymer film is to accelerate the rate of the nucleophilic ring-opening reaction of the epoxide group under benign conditions. It is found that tertiary amine functionality in the poly(glycidyl methacrylate) (PGMA) film significantly increases the rate and degree of the ring-opening reactions. After 2 h of reaction at room temperature, 72% of the epoxy groups are consumed, while the conversion under similar conditions is negligible for the PGMA film.en_US
dc.description.sponsorshipScientific Research Council of Selcuk UniversitySelcuk University [BAP-12101019]en_US
dc.description.sponsorshipThis research was supported by Scientific Research Council of Selcuk University (Project No. BAP-12101019).en_US
dc.identifier.doi10.1002/cvde.201407129en_US
dc.identifier.endpage379en_US
dc.identifier.issn0948-1907en_US
dc.identifier.issn1521-3862en_US
dc.identifier.issue10.12.2020en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage373en_US
dc.identifier.urihttps://dx.doi.org/10.1002/cvde.201407129
dc.identifier.urihttps://hdl.handle.net/20.500.12395/30934
dc.identifier.volume20en_US
dc.identifier.wosWOS:000346660400006en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWILEY-V C H VERLAG GMBHen_US
dc.relation.ispartofCHEMICAL VAPOR DEPOSITIONen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectEpoxideen_US
dc.subjectFunctionalizationen_US
dc.subjectiCVDen_US
dc.subjectRing-openingen_US
dc.subjectTertiary amineen_US
dc.titleInitiated CVD of Tertiary Amine-Containing Glycidyl Methacrylate Copolymer Thin Films for Low Temperature Aqueous Chemical Functionalizationen_US
dc.typeArticleen_US

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