Design of phenanthrimidazole-pendant cyclam and cyclen macrocyclic complex ligands as inorganic hosts: Photophysics, electrochemistry, and bimetallic complex formation

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dc.authorid0000-0001-6753-2958
dc.contributor.authorObali, Aslihan Yilmaz.
dc.date.accessioned2020-03-26T20:20:12Z
dc.date.available2020-03-26T20:20:12Z
dc.date.issued2020
dc.departmentSelçuk Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractNovel ruthenium(II)bpy complexes of the phenanthrimidazole-pendant cyclen and cyclam macrocyclic ligands were synthesized as inorganic host molecules. Inorganic host design was planned as a "complex ligand" form because of its tetraaza macrocyclic unit, which has the ability to coordinate to the metals. Photophysical properties and metal selectivity of inorganic hosts RuL1A and RuL2 complex ligands were investigated by UV-vis and fluorescence spectroscopy in aqueous medium. Among Ag(I), Li(I), Na(I), K(I), Cd(II), Cr(II), Fe(II), Hg(II), Ni(II), Pb(II), Zn(II), Cu(II), Mn(III), and Co(III) metal ions, Fe(II) addition causes spectral changes for both RuL1A and RuL2 complex ligands. Electrochemical studies were performed for RuL1B and also for cis-[Ru(bpy)(2)Cl-2]. Bimetallic complexes [[Ru(bpy)(2)([Ni(2-(4-((1,4,8,11-tetraazacyclotetradecan-1-yl)methyl)phenyl)-1H-imidazo[4,5-f][1,10]phenanthroline])](ClO4)(4), RuL1-NiA and [Ru(bpy)(2)([Ni(2-(4-((1,4,8,11-tetraazacyclotetradecan-1-yl)methyl)phenyl)-1H-imidazo[4,5-f][1,10]phenanthroline])]Cl-4, RuL1-NiB solid complexes were also obtained by the reaction of the RuL1B and Nickel(II).en_US
dc.description.sponsorshipSelcuk University (Konya/TURKEY)Selcuk University [18401062]en_US
dc.description.sponsorshipSelcuk University (Konya/TURKEY), Grant/Award Number: 18401062en_US
dc.identifier.citationObali, A. Y. (2020). Design of Phenanthrimidazole-Pendant Cyclam and Cyclen Macrocyclic Complex Ligands as Inorganic Hosts: Photophysics, Electrochemistry, and Bimetallic Complex Formation. Journal of Heterocyclic Chemistry, 57(1), 400-412.
dc.identifier.doi10.1002/jhet.3793en_US
dc.identifier.endpage412en_US
dc.identifier.issn0022-152Xen_US
dc.identifier.issn1943-5193en_US
dc.identifier.issue1en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage400en_US
dc.identifier.urihttps://dx.doi.org/10.1002/jhet.3793
dc.identifier.urihttps://hdl.handle.net/20.500.12395/38529
dc.identifier.volume57en_US
dc.identifier.wosWOS:000496596200001en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorObali, Aslihan Yilmaz.
dc.language.isoenen_US
dc.publisherWILEYen_US
dc.relation.ispartofJOURNAL OF HETEROCYCLIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectphenanthrimidazole-pendant cyclam
dc.subjectcyclen macrocyclic complex ligands
dc.subjectinorganic hosts
dc.subjectPhotophysics
dc.subjectelectrochemistry
dc.subjectelectrochemistry
dc.titleDesign of phenanthrimidazole-pendant cyclam and cyclen macrocyclic complex ligands as inorganic hosts: Photophysics, electrochemistry, and bimetallic complex formationen_US
dc.typeArticleen_US

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