Fluorinated-cobalt phthalocyanine catalyzed oxygen reduction at liquid/liquid interfaces
Küçük Resim Yok
Tarih
2013
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
PERGAMON-ELSEVIER SCIENCE LTD
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Cobalt fluoro-phthalocyanine (CoFPc) can efficiently catalyze the reduction of oxygen (O-2) by a weak electron donor, namely tetrathiafulvalene (TIT), at the polarized water/1,2-dichloroethane (DCE) interface. Two-phase shake flask experiments and ion transfer voltammetry results suggest that the catalytic reaction proceeds as a proton-coupled electron transfer reduction of oxygen to mainly hydrogen peroxide, where a proton transfer from water to DCE is occurring concomitantly with the electron transfer reaction between TTF and oxygen. (C) 2012 Elsevier Ltd. All rights reserved.
Açıklama
Anahtar Kelimeler
Oxygen reduction, Cobalt fluoro-phthalocyanine, Proton coupled oxygen reduction, Tetrathiafulvalene, Liquid/liquid interface
Kaynak
ELECTROCHIMICA ACTA
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
87
