The first example of calix[4]pyrrole functionalized vic-dioxime ligand: Synthesis, characterization, spectroscopic studies and redox properties of the mononuclear transition metal complexes

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dc.contributor.authorTaner, Bilge
dc.contributor.authorDeveci, Pervin
dc.contributor.authorBereket, Soner
dc.contributor.authorSolak, Ali Osman
dc.contributor.authorOzcan, Emine
dc.date.accessioned2020-03-26T18:05:19Z
dc.date.available2020-03-26T18:05:19Z
dc.date.issued2010
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractNovel calix[4] pyrrole bearing vic-dioxime ligand (LH2) of the general formula, R1R2C2N2O2H2 (where, R-1 = C6H5- and R-2 = C39H50N5-) has been synthesized by the reaction of anti-chlorophenylglyoxime with 3-aminophenylcalix[4] pyrrole at room temperature. The mononuclear Cu(II), Ni(II) and Co(II) complexes of this vic-dioxime ligand were prepared and their structures were confirmed by elemental analysis, FT-IR, TGA and magnetic susceptibility measurements; the HMBC, DEPT, H-1 and C-13 NMR spectra of the LH2 ligand were also reported. The electrochemical property of the complexes was investigated in DMSO by cyclic voltammetry at 200 mV s (1) scan rate. The cyclic voltammetric measurements clearly indicated that Co(LH)(2)center dot 2H(2)O complex differs from the Ni(LH)(2) and Cu(LH)(2) complexes upon the exhibition of quasi-reversible one-electron transfer reduction process in the negative region instead of an irreversible process. (C) 2010 Elsevier B. V. All rights reserved.en_US
dc.description.sponsorshipTUBITAK (Scientific and Technological Research Council of Turkey)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [108T655]en_US
dc.description.sponsorshipThis work was supported by TUBITAK (Scientific and Technological Research Council of Turkey) with project numbers of 108T655.en_US
dc.identifier.doi10.1016/j.ica.2010.08.003en_US
dc.identifier.endpage4023en_US
dc.identifier.issn0020-1693en_US
dc.identifier.issn1873-3255en_US
dc.identifier.issue14en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage4017en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.ica.2010.08.003
dc.identifier.urihttps://hdl.handle.net/20.500.12395/25384
dc.identifier.volume363en_US
dc.identifier.wosWOS:000283051600053en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE SAen_US
dc.relation.ispartofINORGANICA CHIMICA ACTAen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectvic-Dioximesen_US
dc.subjectTransition metal complexesen_US
dc.subjectCalix[4] pyrroleen_US
dc.subject3-Aminophenylcalix[4] pyrroleen_US
dc.subjectCyclic voltammetryen_US
dc.titleThe first example of calix[4]pyrrole functionalized vic-dioxime ligand: Synthesis, characterization, spectroscopic studies and redox properties of the mononuclear transition metal complexesen_US
dc.typeArticleen_US

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