Copper sorption efficiency of p-tetranitrocalix[4]arene based high performance liquid chromatographic column

dc.contributor.authorDurmaz, Fatih
dc.contributor.authorMemon, Fakhar N.
dc.contributor.authorMemon, Shahabuddin
dc.contributor.authorMemon, Ayaz A.
dc.contributor.authorMemon, Naeem A.
dc.contributor.authorKara, Huseyin
dc.date.accessioned2020-03-26T19:23:28Z
dc.date.available2020-03-26T19:23:28Z
dc.date.issued2016
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractPresent study deals with the sorption characteristics of p-tetranitrocalix[4]arene (3) appended silica-based high-performance liquid chromatographic (HPLC) column utilized for preconcentration, determination, and purification of Cu2+ from water. The sorption characteristics of the HPLC column were investigated for Cu2+ in column agreement. The experiments were performed in five steps that were monitored using UV-visible diode-array detector. However, all the HPLC experimental results were reconfirmed by using atomic absorption spectrophotometer. The effect of concentration on the sorption efficiency of the column was evaluated for Cu2+ and data obtained was investigated using Langmuir and Freundlich sorption isotherms. The value of coefficient of determination (R-2), i.e. 0.99, suggested that the Freundlich sorption isotherm was found to be the best fit model for Cu2+. The developed method was validated for system efficiency, accuracy, and precision, while the data obtained revealed that the developed column could be applied for the sorption of Cu2+ with adequate efficiency and repeatability.en_US
dc.description.sponsorshipHigher Education Commission Islamabad [2Ps1-324]; National Centre of Excellence in Analytical Chemistry, University of Sindh, Jamshoro; Higher Education Commission (YOK) of TurkeyMinistry of National Education - Turkeyen_US
dc.description.sponsorshipWe would like to thank Higher Education Commission Islamabad (No. 2Ps1-324) and the National Centre of Excellence in Analytical Chemistry, University of Sindh, Jamshoro, and Higher Education Commission (YOK) of Turkey for the financial support of this work.en_US
dc.identifier.doi10.1080/19443994.2015.1025436en_US
dc.identifier.endpage8941en_US
dc.identifier.issn1944-3994en_US
dc.identifier.issn1944-3986en_US
dc.identifier.issue19en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage8935en_US
dc.identifier.urihttps://dx.doi.org/10.1080/19443994.2015.1025436
dc.identifier.urihttps://hdl.handle.net/20.500.12395/33404
dc.identifier.volume57en_US
dc.identifier.wosWOS:000370065200007en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherDESALINATION PUBLen_US
dc.relation.ispartofDESALINATION AND WATER TREATMENTen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectHPLCen_US
dc.subjectAASen_US
dc.subjectCopperen_US
dc.subjectSorptionen_US
dc.subjectCalixareneen_US
dc.titleCopper sorption efficiency of p-tetranitrocalix[4]arene based high performance liquid chromatographic columnen_US
dc.typeArticleen_US

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