Synthesis and Complex-Formation of New Unsymmetrical Vic-Dioximes
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Dosyalar
Tarih
1995
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
MARCEL DEKKER INC
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
anti-p-Chlorophenylchloroglyoxime (C8H6 Cl-2 N2O2) has been synthesized by chlorination of anti-p-chlorophenylglyoxime. The reaction of C8H6Cl2N2O2 with aryl- or arylalkylamines in ethanol between -10 degrees C and -15 degrees C gives unsymmetrical vic-dioximes, namely, anilino-p-chlorophenylglyoxime (L(1)H(2)), benzylamino-p-chlorophenylglyoxime (L(2)H(2)), p-toluidino-p-chlorophenylglyoxime (L(3)H(2)), p-anisidino-p-chlorophenylglyoxime (L(4)H(2)). The Ni(II) and Cu(II) complexes of these ligands are square-planar while the Co(II) complexes are octahedral with water molecules as axial ligands. H-1 NMR, IR and UV-vis data are given.
Açıklama
Anahtar Kelimeler
Kaynak
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
WoS Q Değeri
N/A
Scopus Q Değeri
N/A
Cilt
25
Sayı
6
Künye
Pekacar, A. I., Ozcan, E., (1995). Synthesis and Complex-Formation of New Unsymmetrical Vic-Dioximes. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 25(6), 859-868. DOI:10.1080/15533179508218266
