Haloalkanes and aromatic hydrocarbons sensing using Langmuir-Blodgett thin film of pillar[5]arene-biphenylcarboxylic acid

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dc.contributor.authorKurşunlu, Ahmed Nuri
dc.contributor.authorAçıkbaş, Yaser
dc.contributor.authorÖzmen, Mustafa
dc.contributor.authorErdoğan, Matem
dc.contributor.authorÇapan, Rıfat
dc.date.accessioned2020-03-26T20:14:28Z
dc.date.available2020-03-26T20:14:28Z
dc.date.issued2019
dc.departmentSelçuk Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractHere, a pillar [5]arene derivative including biphenylcarboxylic acid groups was designed for obtaining a macrocycle with an ideal cavity for volatile organic compounds. The pillar[5]arene -biphenylcarboxylic acid (P5-BPCA) based Langmuir-Blodgett (LB) thin films were produced onto 50 nm thick gold-coated glass and 3.5 MHz quartz crystal substrates to form a thin film chemical sensor element. Surface plasmon resonance (SPR) and Quartz crystal microbalance (QCM) techniques were employed to characterize all the P5-BPCA LB thin film layers. The mass of LB film layer loaded onto a quartz crystal and the resonance frequency shifts per layer were determined to be 711.71 ng per layer (2.68 ng mm(-2)) and 48.24 Hz per layer, respectively. The P5-BPCA LB thin film sensor element was exposed to various haloalkane and aromatic hydrocarbon vapors. The sensitivities of the P5-BPCA LB film sensor were determined between 1.776 and 3.976 Hz ppm(-1). Sensitivity with detection limits were obtained between 0.754 and 1.689 ppm against organic vapors. The results showed that P5-BPCA LB thin film was highly selective with a large response to chloromethane vapor.en_US
dc.description.sponsorshipResearch Foundation of Selcuk UniversitySelcuk University [BAP-16611114]; Research Foundation of Usak UniversityUsak University [UBAP-2017/HD-MF001]en_US
dc.description.sponsorshipWe thank Prof. J.-F. Nierengarten and Dr. I. Nierengarten for their helpful discussions. Financial support for this work is provided by the Research Foundation of Selcuk University (BAP-16611114) and the Research Foundation of Usak University (UBAP-2017/HD-MF001).en_US
dc.identifier.citationKursunlu, A. N., Acikbas, Y., Ozmen, M., Erdogan, M., Capan, R. (2019). Haloalkanes and Aromatic Hydrocarbons Sensing Using Langmuir–Blodgett Thin Film of Pillar [5] arene-biphenylcarboxylic Acid. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 565, 108-117.
dc.identifier.doi10.1016/j.colsurfa.2018.12.050en_US
dc.identifier.endpage117en_US
dc.identifier.issn0927-7757en_US
dc.identifier.issn1873-4359en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage108en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.colsurfa.2018.12.050
dc.identifier.urihttps://hdl.handle.net/20.500.12395/37884
dc.identifier.volume565en_US
dc.identifier.wosWOS:000457062300013en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorKursunlu, Ahmed Nuri.
dc.institutionauthorOzmen, Mustafa.
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE BVen_US
dc.relation.ispartofCOLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectPillarareneen_US
dc.subjectLangmuir-Blodgetten_US
dc.subjectSurface plasmon resonanceen_US
dc.subjectQuartz crystal microbalanceen_US
dc.subjectVolatile organic compoundsen_US
dc.subjectSwellingen_US
dc.titleHaloalkanes and aromatic hydrocarbons sensing using Langmuir-Blodgett thin film of pillar[5]arene-biphenylcarboxylic aciden_US
dc.typeArticleen_US

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