New supramolecular compounds: the complexes of nickel(II), copper(II), cobalt(II), cadmium(II) and zinc(II) with anti- [N-(4-aminophenyl)aza-15-crown-5]-4-(phenoxy)phenylglyoxime ligand

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dc.contributor.authorOzpinar, Kursat
dc.contributor.authorDeveci, Pervin
dc.contributor.authorKilinc, Merve
dc.contributor.authorOzcan, Emine
dc.contributor.authorKaraman, Burcu Dilyuz
dc.contributor.authorKaraarslan, Havva
dc.contributor.authorTaner, Bilge
dc.date.accessioned2020-03-26T19:06:26Z
dc.date.available2020-03-26T19:06:26Z
dc.date.issued2015
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractA new vic-dioxime ligand (1), bearing pendant an azacrown ether moiety and its soluble mononuclear cadmium(II), zinc(II), nickel(II), copper(II) and cobalt(II) complexes were obtained with the metal: ligand ratios of 1: 2 and 1:1. The structures of the ligand and its complexes were verified using Fourier transform infrared (FT-IR), ultraviolet-visible (UV-Vis), mass spectrometry (MS), H-1 and C-13 NMR techniques. More detailed information about the structure of the 1 was provided by the two-dimensional (2D) heteronuclear single quantum coherence and heteronuclear multiple bond correlation techniques. The complexation properties of the ligand 1 were studied in the presence of different cations such as Pb2+, Zn2+, Cu2+, Cr3+, Hg2+, Zn2+, Fe3+ and Al3+ by UV-Vis spectroscopy and H-1 NMR titration methods. All experimental results indicated that the new ligand acts as a selective compound only for Hg+2 cation. The redox behaviour of the complexes, were investigated by cyclic voltammetry at the glassy carbon electrode in 0.1 M tetrabutylamoniumtetrafluoroborate in dimethyl sulfoxide.en_US
dc.description.sponsorshipTUBITAK (Scientific and Technological Research Council of Turkey)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [111T970]; Selcuk UniversitySelcuk University [13401023]en_US
dc.description.sponsorshipThis work was supported by TUBITAK (Scientific and Technological Research Council of Turkey) with project numbers of 111T970, and the Research Fund of Selcuk University Project Number 13401023.en_US
dc.identifier.doi10.1007/s10847-015-0503-1en_US
dc.identifier.endpage415en_US
dc.identifier.issn1388-3127en_US
dc.identifier.issn1573-1111en_US
dc.identifier.issue03.04.2020en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage407en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10847-015-0503-1
dc.identifier.urihttps://hdl.handle.net/20.500.12395/32362
dc.identifier.volume82en_US
dc.identifier.wosWOS:000357572400011en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectSolid and solution state studiesen_US
dc.subjectMetal complexen_US
dc.subjectAzacrown etheren_US
dc.subjectRedox propertyen_US
dc.titleNew supramolecular compounds: the complexes of nickel(II), copper(II), cobalt(II), cadmium(II) and zinc(II) with anti- [N-(4-aminophenyl)aza-15-crown-5]-4-(phenoxy)phenylglyoxime liganden_US
dc.typeArticleen_US

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