The synthesis and metal cation extraction studies of novel polymer-bound calix(aza)crowns

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dc.contributor.authorAkkuş, Gülderen Uysal
dc.contributor.authorMemon, Shahabuddin
dc.contributor.authorGürkaş, Dilek Erol
dc.contributor.authorAslan, Selma
dc.contributor.authorYılmaz, Mustafa
dc.date.accessioned2020-03-26T17:28:17Z
dc.date.available2020-03-26T17:28:17Z
dc.date.issued2008
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThis article describes the synthesis and extraction properties of new calix(aza)crown monomers and their polymer-bound analogues. These compounds have been synthesized by reacting calix-(aza)crowns (4a, 4b and 4c) with Merrifield's resin. Their cation phase-transfer studies were performed by using liquid-liquid extraction procedure. It has been inferred from the observations that monomer 4a shows a good extraction behavior toward selected alkali (Na+, K+, Cs+) and transition metal cations (Cu2+, Co2+, Cd2+, Ni2+, Hg2+, Pb2+), while 4b and 4c prefer Na+ and K+ among alkali metal cations, respectively. The polymer analogues 5a and 5b are efficient extractants for all the selected metal cations; whereas 5c is selective only for transition metal cations. (C) 2007 Elsevier Ltd. All rights reserved.en_US
dc.identifier.doi10.1016/j.reactfunctpolym.2007.10.005en_US
dc.identifier.endpage132en_US
dc.identifier.issn1381-5148en_US
dc.identifier.issue1en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage125en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.reactfunctpolym.2007.10.005
dc.identifier.urihttps://hdl.handle.net/20.500.12395/22750
dc.identifier.volume68en_US
dc.identifier.wosWOS:000252612800014en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE BVen_US
dc.relation.ispartofREACTIVE & FUNCTIONAL POLYMERSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectcalixareneen_US
dc.subjectcalix(aza)crownsen_US
dc.subjectpolymeric calixareneen_US
dc.subjectsolvent extractionen_US
dc.subjectmetal cationsen_US
dc.titleThe synthesis and metal cation extraction studies of novel polymer-bound calix(aza)crownsen_US
dc.typeArticleen_US

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