Complexes of Iron(III) and Chrom(III) Salen and Saloph Schiff Bases with Bridging 2,4,6-tris(4-nitrophenylimino-4'-formylphenoxy)-1,3,5-triazine

Küçük Resim Yok

Tarih

2008

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

TAYLOR & FRANCIS INC

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Four new trinuclear Fe(III) and Cr(III) complexes involving tetradenta Schiff bases N,N'-bis(salicylidene)ethylenediamine-(salenH2) or bis(salicylidene)-o-phenylenediamine-(saloph H2) with 2,4,6-tris(4-nitrophenylimino-4'-formylphenoxy)-1,3,5-triazine (TNPI-TRIPOD) have been synthesized and characterized by means of elemental analysis carrying out 1H-NMR., IR spectroscopy, thermal analyses and magnetic susceptibility measurements. The complexes can also be characterized as high-spin distorted octahedral Fe(III) and Cr(III) bridged by nitro. The nitro play a role as bridges for weak anti-ferromagnetic intramolecular exchange.

Açıklama

Anahtar Kelimeler

Schiff base, triazine, cyanuric chloride, salen, saloph, metal complexes

Kaynak

JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY

WoS Q Değeri

Q3

Scopus Q Değeri

Q2

Cilt

45

Sayı

12

Künye