Oligomeric calix[4]arene-thiacrown ether for toxic heavy metals

dc.contributor.authorTabakci, M
dc.contributor.authorMemon, S
dc.contributor.authorYilmaz, M
dc.contributor.authorRoundhill, DM
dc.date.accessioned2020-03-26T16:55:22Z
dc.date.available2020-03-26T16:55:22Z
dc.date.issued2004
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractA new oligomeric calix[4]arene-thiacrown-4 (5) was synthesized via a condensation reaction of 5,11,17,23-tetra-tert-butyl-25,27-bis-(4-aminobenzyloxy)-calix[4]arene-thiacrown-4 (4) with adipoyl dichloride. In this oligomerization reaction only five/six calix[4]arene-thiacrown-4 units were linked in the oligomeric chain. The complexation studies of 5 were made with liquid-liquid- extraction and solid-liquid-sorption procedures. For comparison, the extraction efficiencies of monomers 1, 3, and 4 to selected transition metals are reported. The selectivity of monomers 3 and 4 toward Cu2+, Hg2+, and Pb2+ was lost after oligomerization in the two-phase extraction systems. (C) 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 186-193, 2004.en_US
dc.identifier.doi10.1002/pola.11004en_US
dc.identifier.endpage193en_US
dc.identifier.issn0887-624Xen_US
dc.identifier.issue1en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage186en_US
dc.identifier.urihttps://dx.doi.org/10.1002/pola.11004
dc.identifier.urihttps://hdl.handle.net/20.500.12395/19140
dc.identifier.volume42en_US
dc.identifier.wosWOS:000187214400020en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherJOHN WILEY & SONS INCen_US
dc.relation.ispartofJOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectcalix[4]areneen_US
dc.subjectthiacrown etheren_US
dc.subjecttransition metal chemistryen_US
dc.subjectsolvent extractionen_US
dc.subjectoligomeric calixareneen_US
dc.titleOligomeric calix[4]arene-thiacrown ether for toxic heavy metalsen_US
dc.typeArticleen_US

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