Synthesis and electrochemical properties of calix[4]arene derivatives containing ferrocene units in the cone and 1,3-alternate conformation

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dc.contributor.authorErdemir, Serkan
dc.contributor.authorDeveci, Pervin
dc.contributor.authorTaner, Bilge
dc.contributor.authorKocyigit, Ozcan
dc.date.accessioned2020-03-26T18:31:28Z
dc.date.available2020-03-26T18:31:28Z
dc.date.issued2012
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractTwo novel calix[4]arene receptors containing ferrocene units in cone (L-1) and 1,3-alternate (L-2) conformations have been synthesized from 25,27-dihydroxy-26,28-bisl(3-aminopropyl)oxy]calix[4]arene 4 or 25,26,27,28-tetra[(3-aminopropyl)oxy]calix[4]arene 6 and ferrocenecarboxaldehyde via condensation, respectively. Their structures have been characterized by H-1, C-13, APT, COSY NMR, FTIR, HSMR, and UV-vis spectral data. The electrochemical behavior of L-1 and L-2 has been investigated in the presence of F-, Cl-, Br-, H2PO4-, CH3COO- anions. Electrochemical studies show that these receptors electrochemically recognize CH3COO-, H2PO4-, and Cl-, anions. Using an UV-vis study, the selectivity to these anions in DMS0 solution was confirmed. (C) 2011 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipResearch Foundation of The Selcuk University (BAP)Selcuk Universityen_US
dc.description.sponsorshipWe thank the Research Foundation of The Selcuk University (BAP) for financial support of this work.en_US
dc.identifier.doi10.1016/j.tet.2011.10.117en_US
dc.identifier.endpage646en_US
dc.identifier.issn0040-4020en_US
dc.identifier.issue2en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage642en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.tet.2011.10.117
dc.identifier.urihttps://hdl.handle.net/20.500.12395/28453
dc.identifier.volume68en_US
dc.identifier.wosWOS:000299443900031en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPERGAMON-ELSEVIER SCIENCE LTDen_US
dc.relation.ispartofTETRAHEDRONen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCalixareneen_US
dc.subjectFerroceneen_US
dc.subjectSchiff baseen_US
dc.subjectAnionen_US
dc.subjectElectrochemicalen_US
dc.titleSynthesis and electrochemical properties of calix[4]arene derivatives containing ferrocene units in the cone and 1,3-alternate conformationen_US
dc.typeArticleen_US

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