Third-order nonlinear optic and optical limiting properties of a MN(III) transition metal complex

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dc.contributor.authorKarakas, Asli
dc.contributor.authorElmali, Ayhan
dc.contributor.authorYahsi, Yasemin
dc.contributor.authorKara, Hulya
dc.date.accessioned2020-03-26T17:18:40Z
dc.date.available2020-03-26T17:18:40Z
dc.date.issued2007
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractN,N'-bis(5-bromosalicylidene)propane-1,2-diamine-O,O',N,N')-manganese(III) chloride transition metal complex has been synthesized and characterized by elemental analysis and UV-vis spectroscopy. Its crystal structure has been determined using X-ray diffraction analysis. To provide an insight into the optical limiting (OL) behavior of the title compound, the third-order nonlinear optical (NLO) properties, one-photon absorption (OPA) and two-photon absorption (TPA) characterizations have been theoretically investigated by means of the time-dependent Hartree-Fock (TDHF), AM1 and configuration interaction (CI) methods, respectively. According to ab initio calculation results, the examined molecule exhibits second hyperpolarizabilities (gamma) with non-zero values at the positions of TPA peaks, implying microscopic third-order optical nonlinearity. The maximum OPA wavelengths recorded by linear optical experiment and quantum mechanical computations are estimated in the UV region to be shorter than 400 nm, showing good optical transparency to the visible light. The TPA cross-sections (delta(omega)) at lambda((2))(max) values indicate that the synthesized compound might possess OL phenomena, which are in accord with the experimental observations on the manganese complexes in the literature.en_US
dc.identifier.doi10.1142/S0218863507003858en_US
dc.identifier.endpage518en_US
dc.identifier.issn0218-8635en_US
dc.identifier.issue4en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage505en_US
dc.identifier.urihttps://dx.doi.org/10.1142/S0218863507003858
dc.identifier.urihttps://hdl.handle.net/20.500.12395/21711
dc.identifier.volume16en_US
dc.identifier.wosWOS:000252521400007en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWORLD SCIENTIFIC PUBL CO PTE LTDen_US
dc.relation.ispartofJOURNAL OF NONLINEAR OPTICAL PHYSICS & MATERIALSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectoptical limitingen_US
dc.subjectthird-order optical nonlinearityen_US
dc.subjecttwo-photon absorptionen_US
dc.subjectAM1en_US
dc.subjectTDHFen_US
dc.subjectCIen_US
dc.titleThird-order nonlinear optic and optical limiting properties of a MN(III) transition metal complexen_US
dc.typeArticleen_US

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