A new Keggin-type polyoxometalate catalyst for degradation of aqueous organic contaminants

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dc.contributor.authorOlgun, Asim
dc.contributor.authorColak, Alper Tolga
dc.contributor.authorGubbuk, I. Hilal
dc.contributor.authorSahin, Onur
dc.contributor.authorKanar, Ebru
dc.date.accessioned2020-03-26T19:33:32Z
dc.date.available2020-03-26T19:33:32Z
dc.date.issued2017
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractIn this study, a new polyoxometalate,K-16[Ni(H2O)(6)](2)[BW12O40]4(center dot)48H(2)O (1) was synthesized at room temperature and characterized by X-ray single crystal diffractions, elemental analyses, IR spectra, and thermo gravimetric analyses (TGA). Crystal structure analysis reveals that compound 1 exhibits a supramolecular structure containing one Keggin-type [BW12O40](4) heteropoly anion. The catalytic properties of this molecule for the degradation of Methyl red (MR), Rhodamine B (RhB), Methyl orange (MO) and Congo red (CR) were investigated. The results show that the compound 1 is a promising catalyst candidate for dye degradation. (C) 2016 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipTUBITAKTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [BIDEB 2210-C]en_US
dc.description.sponsorshipThanks to TUBITAK for providing scholarship to Ebru KANAR with BIDEB 2210-C programme.en_US
dc.identifier.doi10.1016/j.molstruc.2016.12.059en_US
dc.identifier.endpage84en_US
dc.identifier.issn0022-2860en_US
dc.identifier.issn1872-8014en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage78en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.molstruc.2016.12.059
dc.identifier.urihttps://hdl.handle.net/20.500.12395/34735
dc.identifier.volume1134en_US
dc.identifier.wosWOS:000394919100010en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELSEVIERen_US
dc.relation.ispartofJOURNAL OF MOLECULAR STRUCTUREen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectPolyoxometalateen_US
dc.subjectCatalyticen_US
dc.subjectMethyl orangeen_US
dc.subjectRhodamine Ben_US
dc.subjectMethyl reden_US
dc.subjectCongo reden_US
dc.titleA new Keggin-type polyoxometalate catalyst for degradation of aqueous organic contaminantsen_US
dc.typeArticleen_US

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