Asymmetric Star-Shaped Functionalized Triazine Architecture and Its Electrochromic Device Application

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dc.contributor.authorKaratas, Erhan
dc.contributor.authorGuzel, Merve
dc.contributor.authorAk, Metin
dc.date.accessioned2020-03-26T19:34:02Z
dc.date.available2020-03-26T19:34:02Z
dc.date.issued2017
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractA new asymmetric functionalized star shaped triazine derivative, namely 2,2'-((6-(quinolin-8-yloxy)-1,3,5-triazine-2,4-diyl)bis(oxy))bis(9H carbazole) (TQC) was synthesized from 2-hydroxy carbazole and 8-hydroxyquinoline. The electrically conductive PTQC film was synthesized via electropolymerization on ITO in a 0.1 M lithium perchlorate/acetonitrile (LiClO4/ACN) electrolyte-solvent couple. H-1-NMR, FTIR and elemental analysis were used to analyze the structure of the TQC. Both electrochemical and spectroelectrochemical studies of the polymer were examined. PTQC revealed color changes between transparent and dark green in the reduced and oxidized states, respectively. Dual type polymer electrochromic devices (ECDs) based on PTQC and poly(3,4-ethylenedioxythiophene) (PEDOT) have been constructed. A potential range of 0 to 2.5 V was found to be proper for working the PTQC/PEDOT device between transparent and blue colors. The spectroelectrochemistry, electrochromic switching, open circuit memory and stability of the device were studied. The properties of the electrochromic device have been investigated such as spectroelectrochemistry, electrochromic switching, stability and open circuit memory. (C) 2017 The Electrochemical Society. All rights reserved.en_US
dc.description.sponsorshipTUBITAK-BIDEBTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [2218]; PAU-BAPPamukkale University [2017HZDP013]en_US
dc.description.sponsorshipAuthors gratefully thank to the TUBITAK-BIDEB (2218) and PAU-BAP 2017HZDP013 grants.en_US
dc.identifier.doi10.1149/2.0731707jesen_US
dc.identifier.endpageII469en_US
dc.identifier.issn0013-4651en_US
dc.identifier.issn1945-7111en_US
dc.identifier.issue7en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpageII463en_US
dc.identifier.urihttps://dx.doi.org/10.1149/2.0731707jes
dc.identifier.urihttps://hdl.handle.net/20.500.12395/34828
dc.identifier.volume164en_US
dc.identifier.wosWOS:000404397300146en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELECTROCHEMICAL SOC INCen_US
dc.relation.ispartofJOURNAL OF THE ELECTROCHEMICAL SOCIETYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.titleAsymmetric Star-Shaped Functionalized Triazine Architecture and Its Electrochromic Device Applicationen_US
dc.typeArticleen_US

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