Pyrolysis of black cumin seed cake in a fixed-bed reactor

dc.contributor.authorSen, Nejdet
dc.contributor.authorKar, Yakup
dc.date.accessioned2020-03-26T18:15:51Z
dc.date.available2020-03-26T18:15:51Z
dc.date.issued2011
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe black cumin seed cake (BCSC) is a by-product obtained from the black cumin seeds with cold pressing. This by-product can be utilized as a biomass feedstock for conversion to bio-oil with pyrolysis process. The BCSC samples were initially pyrolyzed on a lab-scale pyrolysis system at different values in the ranges of 300-800 degrees C and 0.050-0.300 L min(-1) to determine the effects of operation temperature and N-2 flow rate on the yields on products, respectively. Then, the bio-oil in the highest yield (wB = 44.37%) which was obtained at pyrolysis final temperature (450 degrees C) temperature, heating rate (35 degrees C min(-1)) particle size (dp > 850 mu m), and sweeping flow rate of 0.200 L min(-1) was characterized by Fourier Transform infra-red (FT-IR) spectroscopy, gas chromatography/mass spectrometry (GC-MS) and column chromatography. Consequently, it was shown that the operating temperature and N-2 gas flow rate parameters were effective on the product yields. Also, the important some physico-chemical properties of the pyrolytic oil obtained in high yield were determined as the calorific value of 38.48 MJ kg(-1), the empirical formula of CH1.651O0.105N0.042S0.001, the rich chemical content containing many different chemical groups, and the density of 970.25 kg m(-3), and the viscosity of 63.42 mm(2) s(-1). Based on the determined properties of the pyrolytic oil, it was decided that the use of pyrolytic oil derived from the BCSC may possible be for the production of the alternative liquid fuels and finely chemicals after the necessary improvements. (C) 2011 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipSelcuk University Scientific Research Projects CouncilSelcuk University [06101004]en_US
dc.description.sponsorshipThe authors are grateful to Selcuk University Scientific Research Projects Council for the financial support of this work through the project number of 06101004.en_US
dc.identifier.doi10.1016/j.biombioe.2011.07.019en_US
dc.identifier.endpage4304en_US
dc.identifier.issn0961-9534en_US
dc.identifier.issn1873-2909en_US
dc.identifier.issue10en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage4297en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.biombioe.2011.07.019
dc.identifier.urihttps://hdl.handle.net/20.500.12395/26764
dc.identifier.volume35en_US
dc.identifier.wosWOS:000297035100024en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPERGAMON-ELSEVIER SCIENCE LTDen_US
dc.relation.ispartofBIOMASS & BIOENERGYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectBio-oilen_US
dc.subjectPyrolysisen_US
dc.subjectBlack cumin seed cakeen_US
dc.subjectBiomass energyen_US
dc.subjectCharacterizationen_US
dc.titlePyrolysis of black cumin seed cake in a fixed-bed reactoren_US
dc.typeArticleen_US

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