SYNTHESIS AND CHARACTERIZATION OF S-TRIAZINE CORED TRIPODAL KETO-OXIME AND ITS TRINUCLEAR COMPLEXES

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dc.contributor.authorUysal, Saban
dc.date.accessioned2020-03-26T18:31:28Z
dc.date.available2020-03-26T18:31:28Z
dc.date.issued2012
dc.departmentSelçuk Üniversitesien_US
dc.description.abstract2,4,6-Tris(4-hydroxybenzimino)-1,3,5-triazine (II) has been synthesized by the reaction of 1 equiv. melamine (I) and 3 equiv. 4-hydroxybenzaldehyde and characterized by means of elemental analysis, H-1 NMR, Fourier transform-infrared spectroscopy, and liquid chromatography-mass spectrometry (LC-MS). 2,4,6-tris(4-(2-phenyl-2-keto-hydroxyiminoyloxy)benzimino)-1,3,5-triazine L (III) has been synthesized by the reaction of 1 equiv. II and 3 equiv. chloroisonitrozoacetophenone and characterized by means of the same methods. Four novel trinuclear Fe(III) and Cr(III) complexes involving tetradentate Schiff bases N,N'-bis(salicylidene) ethylenediamine-(salenH(2)) or bis(salicylidene)-o-phenylenediamine(salophen H-2) with L (III) have been synthesized and characterized by means of elemental analysis, Fourier transform-infrared spectroscopy, LC-MS (ESI+), and thermal analyses. The metal ratios of the prepared complexes have been determined using atomic absorption spectroscopy. The aim of the present study is to synthesize novel tridirectional-trinuclear systems and to present their effects on magnetic behavior of [salen or salophenFe(III)/Cr(III)] capped complexes. The complexes have also been characterized as low-spin distorted octahedral Fe(III) and as distorted octahedral Cr(III) bridged by keton-oxime group.en_US
dc.identifier.doi10.1080/00397911.2010.521967en_US
dc.identifier.endpage92en_US
dc.identifier.issn0039-7911en_US
dc.identifier.issn1532-2432en_US
dc.identifier.issue1en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage84en_US
dc.identifier.urihttps://dx.doi.org/10.1080/00397911.2010.521967
dc.identifier.urihttps://hdl.handle.net/20.500.12395/28452
dc.identifier.volume42en_US
dc.identifier.wosWOS:000297977000010en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTAYLOR & FRANCIS INCen_US
dc.relation.ispartofSYNTHETIC COMMUNICATIONSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectKeton-oxime groupsen_US
dc.subjectmelamineen_US
dc.subjectsalenen_US
dc.subjectsalophenen_US
dc.subjectSchiff basesen_US
dc.titleSYNTHESIS AND CHARACTERIZATION OF S-TRIAZINE CORED TRIPODAL KETO-OXIME AND ITS TRINUCLEAR COMPLEXESen_US
dc.typeArticleen_US

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