Synthesis, spectroscopic studies and nonlinear optical behavior of N,N '-bis(2-hydroxy-1-naphthylmethylidene)-1-methyl-1, 2-diaminoethane-N,N ',O,O '-nickel(II)

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dc.contributor.authorUnver, Huseyin
dc.contributor.authorElmali, Ayhan
dc.contributor.authorKarakas, Ash
dc.contributor.authorKara, Hulya
dc.contributor.authorDonmez, Emine
dc.date.accessioned2020-03-26T17:04:27Z
dc.date.available2020-03-26T17:04:27Z
dc.date.issued2006
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractA Schiff base complex N,N'-bis(2-hydroxy-1-naphthylmethylidene)-1-methyl-1,2- diaminoethane-N,N',O,O'-nickel(II) has been synthesized. The title compound has been characterized by FT-IR and UV-vis spectroscopies. The UV-vis experiments indicate that the compound has solvatochromism in the UV region, implying non-zero molecular first hyperpolarizability. To investigate microscopic second-order nonlinear optical (NLO) behavior of the examined complex, the electric dipole moments (mu) and the first static hyperpolarizabilities (beta) were computed using Finite Field second-order Moller Plesset (FF MP2) perturbation procedure. According to ab initio quantum mechanical calculations, the title complex exhibits non-zero P values, revealing microscopic second-order NLO behavior. (c) 2006 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.molstruc.2006.03.089en_US
dc.identifier.endpage22en_US
dc.identifier.issn0022-2860en_US
dc.identifier.issue01.03.2020en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage18en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.molstruc.2006.03.089
dc.identifier.urihttps://hdl.handle.net/20.500.12395/20704
dc.identifier.volume800en_US
dc.identifier.wosWOS:000242743600002en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE BVen_US
dc.relation.ispartofJOURNAL OF MOLECULAR STRUCTUREen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectnickel(II) complexen_US
dc.subjectUV-vis spectroscopyen_US
dc.subjectFT-IRen_US
dc.subjectelectric dipole momenten_US
dc.subjectstatic first hyperpolarizabilityen_US
dc.titleSynthesis, spectroscopic studies and nonlinear optical behavior of N,N '-bis(2-hydroxy-1-naphthylmethylidene)-1-methyl-1, 2-diaminoethane-N,N ',O,O '-nickel(II)en_US
dc.typeArticleen_US

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