Synthesis, Characterization, Thermal and Redox Properties of a Vic-Dioxime and Its Metal Complexes
Yükleniyor...
Dosyalar
Tarih
2010
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
TAYLOR & FRANCIS LTD
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
A new vic-dioxime ligand containing benzophenone hydrazone units, N'-(benzophenone hydrazone)glyoxime [LH2] has been prepared from benzophenone hydrazone and anti-chloroglyoxime in absolute ethanol. Mononuclear nickel(II), cobalt(II), copper(II), zinc(II), and cadmium(II) complexes were also synthesized. Ligand and complexes were characterized by elemental analyses, FT-IR, 1H NMR, and 13C NMR spectroscopy, magnetic moments, and DTA/TG techniques. On the basis of the magnetic and spectral evidences a square-planar geometry for Ni(II) and Cu(II) complexes, tetrahedral for Cd(II) and Zn(II) complexes, and octahedral for Co(II) complex were proposed. Redox behaviors of ligand and its complexes were also investigated by cyclic voltammetry at the glassy carbon electrode.
Açıklama
Anahtar Kelimeler
Vic-Dioxime, Benzophenone Hydrazone, Transition Metal Complexes, DTA, TG Techniques, Cyclic Voltammetry
Kaynak
Journal of Coordination Chemistry
WoS Q Değeri
Q2
Scopus Q Değeri
Q3
Cilt
63
Sayı
17
Künye
Uçar, A., Deveci, P., Taner, B., Fındık, M., Bereket, S., Özcan, E., Solak, A. O., (2010). Synthesis, Characterization, Thermal and Redox Properties of a Vic-Dioxime and Its Metal Complexes. Journal of Coordination Chemistry, 63(17), 3083-3092.
DOI: 10.1080/00958972.2010.504259
