Facilitated Transport of Cr(VI) Through a Bulk Liquid Membrane Containing P-tert-Butylcalix[4]arene Amine Derivative as a Carrier

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dc.contributor.authorAlpoğuz, Hamza Korkmaz
dc.contributor.authorKaya, Ahmet
dc.contributor.authorTabakçı, Begüm
dc.contributor.authorYılmaz, Aydan
dc.date.accessioned2020-03-26T17:48:43Z
dc.date.available2020-03-26T17:48:43Z
dc.date.issued2010
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe facilitated transport of Cr(VI) through a bulk liquid membrane (BLM) is investigated, using the by p-tert-butylcalix[4]arene amine derivative as mobile carrier. The transport efficiency of Cr(VI) by p-tert-butylcalix[4]arene amine derivative was investigated under various experimental conditions such as the influence of pH on the donor and the acceptor phase, effect of Cr(VI) and carrier concentration, the type of solvent, the stirring speed, and the temperature. The kinetic parameters (k1, k2, [image omitted], tmax, [image omitted], [image omitted]) were calculated for the interface reactions assuming two consecutive, irreversible first order reactions. The activation energy values are calculated as 5.94 and 12.51kJ mol-1 for extraction and reextraction, respectively. The values of the calculated activation energy indicate that the process is diffusionally controlled by species.en_US
dc.description.sponsorshipScientifical and Research Foundation of Pamukkale University, Denizli-TurkeyPamukkale University [2007 FBE 019]; Research Foundation of Selcuk University, Konya-TurkeySelcuk Universityen_US
dc.description.sponsorshipThis work was supported by the Scientifical and Research Foundation of Pamukkale University, Denizli-Turkey (Grant No: 2007 FBE 019) and the Research Foundation of Selcuk University, Konya-Turkey.en_US
dc.identifier.citationAlpoğuz, H. K., Kaya, A., Tabakçı, B., Yılmaz, A., (2010). Facilitated Transport of Cr(VI) Through a Bulk Liquid Membrane Containing P-tert-Butylcalix[4]arene Amine Derivative as a Carrier. Separation Science and Technology, 45(8), 1121-1129. Doi: 10.1080/01496391003697424
dc.identifier.doi10.1080/01496391003697424en_US
dc.identifier.endpage1129en_US
dc.identifier.issn0149-6395en_US
dc.identifier.issue8en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1121en_US
dc.identifier.urihttps://dx.doi.org/10.1080/01496391003697424
dc.identifier.urihttps://hdl.handle.net/20.500.12395/24930
dc.identifier.volume45en_US
dc.identifier.wosWOS:000277728100013en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorAlpoğuz, Hamza Korkmaz
dc.institutionauthorKaya, Ahmet
dc.language.isoenen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.ispartofSeparation Science and Technologyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectbulk liquid membraneen_US
dc.subjectCr(VI)en_US
dc.subjectkinetic modelen_US
dc.subjectp-tert-butylcalix[4]areneen_US
dc.titleFacilitated Transport of Cr(VI) Through a Bulk Liquid Membrane Containing P-tert-Butylcalix[4]arene Amine Derivative as a Carrieren_US
dc.typeArticleen_US

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