Poly (dithienylpyrrole) / Keggin type (nBu(4)N)(3)[PW9O34(tBuSiOH)(3)] hybrid material: Enhanced optical and electrical properties of conjugated polymers via polyoxometalates

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dc.contributor.authorSoğancı, Tuğba
dc.contributor.authorTorlak, Yasemin
dc.contributor.authorAk, Metin
dc.contributor.authorErsöz, Mustafa
dc.date.accessioned2020-03-26T19:55:13Z
dc.date.available2020-03-26T19:55:13Z
dc.date.issued2018
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractConductive polymers with unique optical and electrical properties are ideal matrices for redox active inorganic materials in the development of flexible, easily processable conductive materials for promising applications. Polyoxometalates (POMs) are a class of inorganic materials consisting of soluble, anionic metal oxide clusters of transition metals exhibiting enormous versatility in their structural features and properties. The properties as well as the processability of POM clusters can be enhanced by combining them with conducting polymers, either electrostatically or covalently, resulting in organically modified POMs, which have found extensive applications in diverse fields. For this purpose, we electrochemically incorporated a Keggin type POM anion, (nBu(4)N)(3)[PW9O34(tBuSiOH)(3)], into a dithienyl pyrrole based conducting polymer (pDOB). Obtained organicinorganic hybrid composite film has superior optical and electrical properties when compared to PDOB. Also composite film with advantages such as high optical contrast, low response time, long-term stability etc. is promising to meet the requirement for constructing smart windows, supercapacitors and electrochromic devices.en_US
dc.identifier.doi10.1016/j.synthmet.2018.06.015en_US
dc.identifier.endpage60en_US
dc.identifier.issn0379-6779en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage54en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.synthmet.2018.06.015
dc.identifier.urihttps://hdl.handle.net/20.500.12395/36873
dc.identifier.volume244en_US
dc.identifier.wosWOS:000444932100008en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE SAen_US
dc.relation.ispartofSYNTHETIC METALSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectPolyoxometalatesen_US
dc.subjectElectrochemistryen_US
dc.subjectConducting polymeren_US
dc.subjectElectrochromicen_US
dc.subjectSpectroelectrochemistryen_US
dc.titlePoly (dithienylpyrrole) / Keggin type (nBu(4)N)(3)[PW9O34(tBuSiOH)(3)] hybrid material: Enhanced optical and electrical properties of conjugated polymers via polyoxometalatesen_US
dc.typeArticleen_US

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