QCM sensors coated with calix[4]arenes bearing sensitive chiral moieties for chiral discrimination of 1-phenylethylamine enantiomers

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dc.contributor.authorOzcelik, Egemen.
dc.contributor.authorTemel, Farabi.
dc.contributor.authorErdemir, Serkan.
dc.contributor.authorTabakci, Begum.
dc.contributor.authorTabakci, Mustafa.
dc.date.accessioned2020-03-26T20:19:11Z
dc.date.available2020-03-26T20:19:11Z
dc.date.issued2019
dc.departmentSelçuk Üniversitesi, Mühendislik Fakültesi, Kimya Mühendisliği Bölümüen_US
dc.description.abstractThis article describes the enantiomeric discrimination properties of new chiral calix[4]arene derivatives bearing (S)-/(R)-1-phenylethylamine moieties (5a and 5b, respectively) towards the 1-phenylethylamine enantiomers on QCM surface. Initial experiments demonstrated that the 5b coated QCM sensor was the most effective sensing material for enantiomeric discrimination of (R)-/(S)-1-phenylethylamine by exhibiting much more sensing ability towards (R)-enantiomer than (S)-enantiomer. Sensitivity, detection limit and time constant of the 5b coated QCM sensor has been were calculated as 0.082 Hz/mu M, 2.7 mu M, and 319.2 s, respectively. Additionally, effects of calixarene content and different coating technique on enantiomeric discrimination, and Langmuir and Freundlich isotherms of the sensing results also were studied. As a result, it has been demonstrated that the coating of QCM sensor with a chiral calix[4]arene (5b) having (S)-1-phenylethylamine moieties provides substantially enantiomeric discrimination of 1-phenylethylamine enantiomers.en_US
dc.description.sponsorshipTechnical Research Council of Turkey (TUBITAK-Grant) [115Z249]; Research Foundation of the Selcuk UniversitySelcuk University [16401003]; Konya, Turkeyen_US
dc.description.sponsorshipWe thank the Technical Research Council of Turkey (TUBITAK-Grant No. 115Z249) and the Research Foundation of the Selcuk University (SUBAP-Grant No. 16401003), Konya, Turkey and for financial support of this work produced from Egemen Ozcelik's M.Sc. Thesis.en_US
dc.identifier.citationOzcelik, E., Temel, F., Erdemir, S., Tabakci, B., Tabakci, M. (2019). QCM Sensors Coated with Calix[4]arenes Bearing Sensitive Chiral Moieties for Chiral Discrimination of 1-phenylethylamine Enantiomers. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 95(1), 35-48.
dc.identifier.doi10.1007/s10847-019-00892-zen_US
dc.identifier.endpage48en_US
dc.identifier.issn1388-3127en_US
dc.identifier.issn1573-1111en_US
dc.identifier.issue1en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage35en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10847-019-00892-z
dc.identifier.urihttps://hdl.handle.net/20.500.12395/38139
dc.identifier.volume95en_US
dc.identifier.wosWOS:000485967900003en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorOzcelik, Egemen.
dc.institutionauthorTemel, Farabi.
dc.institutionauthorTabakci, Mustafa.
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subject1-Phenylethylamineen_US
dc.subjectOrganic coatingsen_US
dc.subjectCalixareneen_US
dc.subjectEnantiomeric discriminationen_US
dc.subjectQuartz crystal microbalance sensoren_US
dc.titleQCM sensors coated with calix[4]arenes bearing sensitive chiral moieties for chiral discrimination of 1-phenylethylamine enantiomersen_US
dc.typeArticleen_US

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