Synthesis of Novel Lactam Ionophores Containing Crown Ether Moieties and Investigation of Their Extraction Abilities Towards Heavy Metal Cations

Yükleniyor...
Küçük Resim

Tarih

2010

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

SPRINGER

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

The article describes the syntheses and extraction properties of new lactam ionophores. These lactam derivatives were easily synthesized via aminolysis of dimethyl 2,2'-(6,6'-methylenebis(2-tert-butyl-4-methyl-6,1-phenylene)bis(oxy))diacetate or dimethyl 2,2'-(2,2'-methylenebis(4-chloro-2,1-phenylene))bis(oxy)diacetate with corresponding diamine compounds at one step. The extraction studies of lactam ionophores were performed toward dichromate anion and alkaline and transition metals such as Li+, Na+, K+, Co2+, Hg2+ and Pb2+. All the structures of the ionophores were confirmed by spectroscopic techniques and elemental analysis.

Açıklama

Anahtar Kelimeler

Crown Ether, Lactam, Heavy Metal, Liquid-Liquid Extraction

Kaynak

Journal of Inclusion Phenomena and Macrocyclic Chemistry

WoS Q Değeri

Q2

Scopus Q Değeri

Q3

Cilt

68

Sayı

Künye

Ertul, Ş., (2010). Synthesis of Novel Lactam Ionophores Containing Crown Ether Moieties and Investigation of Their Extraction Abilities Towards Heavy Metal Cations. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 68, 85-91. DOI: 10.1007/s10847-010-9736-1