The Synthesis and Characterization of s-Triazine-Cored and [Fe(III)Salen]-Capped Polymer Complexes

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dc.contributor.authorKaratas, Erhan
dc.contributor.authorUcan, Halil Ismet
dc.date.accessioned2020-03-26T18:17:17Z
dc.date.available2020-03-26T18:17:17Z
dc.date.issued2011
dc.departmentSelçuk Üniversitesien_US
dc.description.abstract2,4,6-Trichloro-1,3,5-triazine (cyanuric chloride, C(3)N(3)Cl(3), 1) was used as the starting material. 2-(4-Carboxyphenylamino)-4,6-dichloro-1,3,5-triazine (2) was obtained from the reaction of cyanuric chloride with 4-aminobenzoic acid in the presence of sodium bicarbonate in acetone. A mononuclear complex (4) was obtained by reacting 2 and [FeSalen](2)O (3). A series of polymeric compounds was obtained by reacting 4 with a series of diamines. The polymeric complexes were characterized by elemental analysis, AAS, FT-IR, (1)H NMR, TGA and magnetic susceptibility measurements. The complexes are low-spin, distorted octahedral Fe(III) species that are bridged by carboxylic acids. The [FeSalen]-containing compounds may have the electronic structure t (2g) (5) e (g) (0) . All the complexes have six coordination and are polymeric.en_US
dc.description.sponsorshipFoundation of Selcuk UniversitySelcuk University [2005/05101005]en_US
dc.description.sponsorshipWe thank the Scientific Research Projects Foundation of Selcuk University (SUBAP-Grant Number 2005/05101005) for financial support of this work produced from a part of Erhan Karatas's M.Sc Thesis.en_US
dc.identifier.doi10.1007/s10904-011-9503-9en_US
dc.identifier.endpage693en_US
dc.identifier.issn1574-1443en_US
dc.identifier.issue3en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage688en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10904-011-9503-9
dc.identifier.urihttps://hdl.handle.net/20.500.12395/27007
dc.identifier.volume21en_US
dc.identifier.wosWOS:000294804500037en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjects-Triazineen_US
dc.subjectSalenen_US
dc.subjectSchiff baseen_US
dc.subjectPolymer complexesen_US
dc.titleThe Synthesis and Characterization of s-Triazine-Cored and [Fe(III)Salen]-Capped Polymer Complexesen_US
dc.typeArticleen_US

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