Investigation of Dipodal oxy-Schiff base and its salen and salophen Fe(III)/Cr(III)/Mn(III) Schiff bases (N2O2) caped complexes and their magnetic and thermal behaviors
Küçük Resim Yok
Tarih
2014
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
ELSEVIER
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Six new dinuclear Fe(III)/Cr(III)/Mn(III) complexes have been involved tetradentate (N2O2) Schiff bases (salenH(2)) and (salophenH(2)) with 2,4-bis(4-hydroxyphenylimino-4'-formylphenoxy)-6-methoxy-1,3, 5-triazine have been synthesized. The complexes were characterized as high-spin (S = 5/2) distorted trigonal bipyramidal salen/salophenFe(III) bridged, distorted trigonal bipyramidal (S = 3/2) salen/salophenCr(III) and high-spin distorted trigonal bipyramidal (S = 2) salen/salophenMn(III) by OH- groups. The structures of ligand and complexes were identified by using elemental analysis, thermal analysis, magnetic susceptibility, LC-MS, ICP-AES, H-1 NMR and FT-IR spectral data. (C) 2014 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
Salen, Salophen, Schiff base, s-Triazine, Fe(III), Cr(III)
Kaynak
JOURNAL OF MOLECULAR STRUCTURE
WoS Q Değeri
Q3
Scopus Q Değeri
Q2
Cilt
1065
