Double doping synergy to improve structural, morphological, optical, and electrical properties of solution-based Cd and M (M: Pb, Sn, Bi) double doped nanocrystalline copper oxide films

Yükleniyor...
Küçük Resim

Tarih

2019

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

SPRINGER HEIDELBERG

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

In this study, nanostructured CuO, Cd0.01Cu0.99O and Cu0.98Cd0.01M0.01O (M: Pb, Bi, Sn) films were synthesized using the successive ionic layer adsorption and reaction technique. The effects of Cd-doping, Sn, Pb, and Bi double doping on the structural, morphological, optical, and electrical properties were systematically investigated via X-ray diffraction (XRD), scanning electron microscopy (SEM), UV-Vis spectroscopy, and current-voltage (I-V) measurements, respectively. XRD results show that the peak intensity, crystallite size, and texture coefficient of the films changed intensely with double doping. SEM images reveal that the surface morphology of the nanostructures changed with the kind of dopant materials due to the differences in ionic radius. Energy dispersive X-ray spectroscopy studies confirmed the presence of Cd2+, Sn4+, Pb2+, and Bi+5 in the doped films. The estimated average optical band gap energies of the CuO samples varied from 1.366 to 1.480 eV with double doping. The lowest average electrical resistivity of 1.21 x 10(6) ohm cm was found for the Bi-0.01 Cd0.01Cu0.98O sample.

Açıklama

Anahtar Kelimeler

solution-based, nanocrystalline, copper oxide films, Cd

Kaynak

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING

WoS Q Değeri

Q3

Scopus Q Değeri

Q2

Cilt

125

Sayı

12

Künye

Sahin, B., Aydin, R. (2019). Double Doping Synergy to Improve Structural, Morphological, Optical, and Electrical Properties of Solution-Based Cd and M (M: Pb, Sn, Bi) Double Doped Nanocrystalline Copper Oxide Films. Applied Physics A, 125(12), 1-10.