The Synthesis of Four New Unsymmetrical Vic-Dioximes and Their Complexes with Some Transition Metals
Yükleniyor...
Dosyalar
Tarih
1992
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
MARCEL DEKKER INC
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In this study, anti-p-tolylchloroglyoxime (PTCGH2) has been synthesized by chlorination Of anti-2-tolylglyoxime. The reaction of PTCGH2 with suitable arylamines in ethanol between -10-degrees-C and -15-degrees-C gives unsymmetrical vic-dioximes, namely, o-toluidino-2-tolYlglyoxime (C16H17N3O2), 1-naphthylamino-p-tolylglyoxime (C19H17N3O2), 1,1'-biphenyl-4-amino-4'-amino-p-tolylglYoxime (C21H20N4O2), N-(2-methylpyridyl)amino-p-tolylglyoxime (C15H16N4O2). The Cu(II) and Ni(II) complexes of these ligands are square-planar while the Co(II) complexes are octahedral with water molecules as axial ligands. H-1-NMR, mass and IR spectra and elemental analyses data are given.
Açıklama
Anahtar Kelimeler
Kaynak
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
WoS Q Değeri
N/A
Scopus Q Değeri
N/A
Cilt
22
Sayı
8
Künye
Sevindir, Cahit H., Mirzaoğlu, R., (1992). The Synthesis of Four New Unsymmetrical Vic-Dioximes and Their Complexes with Some Transition Metals. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 22(8), 1129-1139. DOI: 10.1080/15533179208020257
