The Synthesis and Characterization of Star Shaped Metal Complexes of Triazine Cored Schiff Bases: Their Thermal Decompositions and Magnetic Moment Values

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dc.contributor.authorUysal, Saban
dc.contributor.authorKursunlu, Ahmed Nuri
dc.date.accessioned2020-03-26T18:17:17Z
dc.date.available2020-03-26T18:17:17Z
dc.date.issued2011
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractTripodal ligand III, 2,4,6-tris(4-hydroxybenzimino)-1,3,5-triazine, was synthesized by reacting melamine with 4-hydroxybenzaldehyde. (E)-4-Bromo-2-((2-bromoethylimino)-methyl)phenol VI was obtained by reaction of 5-bromo-2-hydroxybenzaldehyde and 2-bromoethanamine hydrochloride. Melamine cored tripodal Schiff base VII (H(3)L) was synthesized by reacting III with VI. Tripodal metal complexes were obtained by reacting H(3)L and transition metal salts. The complexes were characterized by elemental analyses, FT-IR, (1)H NMR and LC-MS spectroscopy, thermal analyses and magnetic measurements. Finally, metal ratios of the complexes were determined by atomic absorption spectroscopy. The complexes are square-planar low-spin (S = 1/2) Co(II), diamagnetic square-planar Ni(II), square-planar (S = 1/2) Cu(II) and diamagnetic tetrahedral Zn(II).en_US
dc.identifier.doi10.1007/s10904-011-9459-9en_US
dc.identifier.endpage296en_US
dc.identifier.issn1574-1443en_US
dc.identifier.issue2en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage291en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10904-011-9459-9
dc.identifier.urihttps://hdl.handle.net/20.500.12395/27006
dc.identifier.volume21en_US
dc.identifier.wosWOS:000290801600011en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectHeterocyclic compoundsen_US
dc.subjectSchiff basesen_US
dc.subjectMetal complexesen_US
dc.subjectMelamineen_US
dc.subjectMagnetic susceptibilityen_US
dc.titleThe Synthesis and Characterization of Star Shaped Metal Complexes of Triazine Cored Schiff Bases: Their Thermal Decompositions and Magnetic Moment Valuesen_US
dc.typeArticleen_US

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