Interfacial Transfer of Cd2+ Assisted by 4 '-Morpholino-Acetophenone-4-Phenyl-3-Thiosemicarbazone Across the Water/1,2-Dichloroethane Interface

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dc.contributor.authorBingöl, Haluk
dc.contributor.authorAtalay, Tevfik
dc.date.accessioned2020-03-26T17:49:13Z
dc.date.available2020-03-26T17:49:13Z
dc.date.issued2010
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe assisted transfer of heavy metal ions by interfacial complexation with 4'-morpholinoacetophenone-4-phenyl-3-thiosemicarbazone (MAPPT) at the interface between two immiscible electrolyte solutions (ITIES) was studied by cyclic voltammetry. The voltammograms obtained across the water/1,2-dichloroethane interface using the MAPPT ligand in the organic phase shows that the assisted metal ion transfers have different nature for different ions. The quasi-reversible voltammetric peak of the Cd2+ ion was obtained and is discussed in detail. The dependence of the half-wave transfer potential on MAPPT concentration showed that the equilibrium is effectively displaced towards a 1:3 (metal:ligand) stoichiometry with an association constant of log beta(0) = 15.46 (+/- 0.11) for the Cd2+ ion, corresponding to the TIC/TID mechanism.en_US
dc.description.sponsorshipSelcuk UniversitySelcuk University [2003/151, 05101013]en_US
dc.description.sponsorshipThe authors are grateful to the grant sponsored by the Scientific Research Projects (BAP) of Selcuk University (No. 2003/151 and 05101013).en_US
dc.identifier.citationBingöl, H., Atalay, T., (2010). Interfacial Transfer of Cd2+ Assisted by 4 '-Morpholino-Acetophenone-4-Phenyl-3-Thiosemicarbazone Across the Water/1,2-Dichloroethane Interface. Central European Journal of Chemistry, 8(5), 1134-1139. Doi: 10.2478/s11532-010-0089-9
dc.identifier.doi10.2478/s11532-010-0089-9en_US
dc.identifier.endpage1139en_US
dc.identifier.issn1895-1066en_US
dc.identifier.issue5en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage1134en_US
dc.identifier.urihttps://dx.doi.org/10.2478/s11532-010-0089-9
dc.identifier.urihttps://hdl.handle.net/20.500.12395/25007
dc.identifier.volume8en_US
dc.identifier.wosWOS:000283508200021en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorBingöl, Haluk
dc.institutionauthorAtalay, Tevfik
dc.language.isoenen_US
dc.publisherVersitaen_US
dc.relation.ispartofCentral European Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectThiosemicarbazoneen_US
dc.subjectCyclic voltammetryen_US
dc.subjectAssociation constanten_US
dc.subjectCd2+en_US
dc.subjectITIESen_US
dc.titleInterfacial Transfer of Cd2+ Assisted by 4 '-Morpholino-Acetophenone-4-Phenyl-3-Thiosemicarbazone Across the Water/1,2-Dichloroethane Interfaceen_US
dc.typeArticleen_US

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