A novel vic-dioxime ligand and its Ni(II), Cu(II) and Co(II) complexes containing calix[4]pyrrole moiety: synthesis, characterization and redox properties

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dc.contributor.authorTaner, Bilge
dc.contributor.authorDeveci, Pervin
dc.contributor.authorOzcan, Emine
dc.contributor.authorSolak, Ali Osman
dc.date.accessioned2020-03-26T18:23:36Z
dc.date.available2020-03-26T18:23:36Z
dc.date.issued2012
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractA new calix[4]pyrrole functionalized vic-dioxime, 3-(4-methyl-9,9,14,14,19,19-hexaethylcalix[4]pyrrole)benzoaminoglyoxime (LH2) was synthesized from anti-chloroglyoxime and 3-aminophenyl-calix[4]pyrrole at room temperature. The mononuclear complexes {nickel(II), copper(II) and cobalt(II)} of this vic-dioxime ligand were prepared and their structures were confirmed by elemental analysis, IR and UV-Vis spectrophotometry, magnetic susceptibility; the MS, H-1 and C-13 NMR spectra of the LH2 ligand and its Ni(II) complex were also recorded. The experimental results indicated that the ligand:metal ratio was 2:1 in the cases of Ni(II), Cu(II) and Co(II) complexes as is with most vic-dioximes. Electrochemical properties of the ligand, and its complexes were investigated in DMSO solution by cyclic voltammetry at 200 mV s(-1) scan rate.en_US
dc.description.sponsorshipTUBITAK (Scientific and Technological Research Council of Turkey)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [108T655]; Research Fund of Selcuk UniversitySelcuk University [08101031]en_US
dc.description.sponsorshipThis work was supported by TUBITAK (Scientific and Technological Research Council of Turkey) with project numbers of 108T655 and the Research Fund of Selcuk University Project Number: 08101031 under thesis.en_US
dc.identifier.doi10.1007/s10847-012-0131-yen_US
dc.identifier.endpage396en_US
dc.identifier.issn1388-3127en_US
dc.identifier.issn1573-1111en_US
dc.identifier.issue01.04.2020en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage391en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10847-012-0131-y
dc.identifier.urihttps://hdl.handle.net/20.500.12395/27690
dc.identifier.volume74en_US
dc.identifier.wosWOS:000306946700040en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectOximeen_US
dc.subjectvic-Dioximeen_US
dc.subjectTransition metal complexen_US
dc.subjectCalix[4]pyrroleen_US
dc.subjectCyclic voltammetryen_US
dc.titleA novel vic-dioxime ligand and its Ni(II), Cu(II) and Co(II) complexes containing calix[4]pyrrole moiety: synthesis, characterization and redox propertiesen_US
dc.typeArticleen_US

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