New copper(II) and nickel(II) complexes of 4-morpholinoaceto-phenone thiosemicarbazone: Structural, electrochemical and antimicrobial studies

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dc.contributor.authorBingöl, Haluk
dc.contributor.authorCoşkun, Ahmet
dc.contributor.authorAkgemci, Emine Güler
dc.contributor.authorKaya, Baştürk
dc.contributor.authorAtalay, Tevfik
dc.date.accessioned2020-03-26T17:17:45Z
dc.date.available2020-03-26T17:17:45Z
dc.date.issued2007
dc.departmentSelçuk Üniversitesien_US
dc.description.abstract4-Morpholinoacetophenone thiosemicarbazone, MAPT, and its nickel(II) and copper(II) complexes have been prepared and characterized by elemental analysis, magnetic susceptibility, spectral methods (FT-IR, H-1 NMR) and cyclic voltammetry. Electrochemical behaviors of the complexes have been studied by cyclic voltammetry in DMF media showing metal centered reduction processes for both of them. The redox properties, nature of the electrode processes and the stability of the complexes were discussed. [Cu(MAPT)(2)]Cl-2 complex shows Cu(II)/Cu(I) couple and quasi-reversible wave associated with the Cu(III)/Cu(II) process. The reduction/oxidation potential values depend on the structures of complexes. Also, the antimicrobial activities of these complexes were determined against S. aureus, E. coli and B. subtilis.en_US
dc.identifier.doi10.1002/cjoc.200790060en_US
dc.identifier.endpage311en_US
dc.identifier.issn1001-604Xen_US
dc.identifier.issn1614-7065en_US
dc.identifier.issue3en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage307en_US
dc.identifier.urihttps://dx.doi.org/10.1002/cjoc.200790060
dc.identifier.urihttps://hdl.handle.net/20.500.12395/21490
dc.identifier.volume25en_US
dc.identifier.wosWOS:000244805800009en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWILEY-V C H VERLAG GMBHen_US
dc.relation.ispartofCHINESE JOURNAL OF CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectthiosemicarbazoneen_US
dc.subjectmetal complexesen_US
dc.subjectspectraen_US
dc.subjectcyclic voltammetryen_US
dc.subjectantimicrobial activityen_US
dc.titleNew copper(II) and nickel(II) complexes of 4-morpholinoaceto-phenone thiosemicarbazone: Structural, electrochemical and antimicrobial studiesen_US
dc.typeArticleen_US

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