A calix[4]arene derived dibenzonitrile receptor modified at its "lower rim" by a polymerizable group

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Küçük Resim

Tarih

2004

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

TAYLOR & FRANCIS INC

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

The present work describes the synthesis of a new monomeric dibenzonitrile derivative of p-tert-butylcalix[4]arene containing a polymerizable group at its lower rim. This monomer with an acryl amide group has been copolymerized with styrene yielding a linear polymer with pendant calixarene groups. Extraction studies with this monomer and its copolymer show no selectivity for metal cations. Nevertheless, dibenzonitrile groups with calixarene moiety provide a suitable binding site for transferring metal salt (NaHCr2O7) as an ion-pair.

Açıklama

Anahtar Kelimeler

copolymer, calixarene, solvent extraction, transition metal, dichromate anions

Kaynak

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY

WoS Q DeÄŸeri

Q3

Scopus Q DeÄŸeri

Q2

Cilt

A41

Sayı

7

Künye