A calix[4]arene derived dibenzonitrile receptor modified at its "lower rim" by a polymerizable group
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Dosyalar
Tarih
2004
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
TAYLOR & FRANCIS INC
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
The present work describes the synthesis of a new monomeric dibenzonitrile derivative of p-tert-butylcalix[4]arene containing a polymerizable group at its lower rim. This monomer with an acryl amide group has been copolymerized with styrene yielding a linear polymer with pendant calixarene groups. Extraction studies with this monomer and its copolymer show no selectivity for metal cations. Nevertheless, dibenzonitrile groups with calixarene moiety provide a suitable binding site for transferring metal salt (NaHCr2O7) as an ion-pair.
Açıklama
Anahtar Kelimeler
copolymer, calixarene, solvent extraction, transition metal, dichromate anions
Kaynak
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
WoS Q DeÄŸeri
Q3
Scopus Q DeÄŸeri
Q2
Cilt
A41
Sayı
7