Facilitated Transfer of Alkali and Alkaline-Earth Metal Ions by a Calix[4]arene Derivative Across Water/1,2-Dichloroethane Microinterface: Amperometric Detection of Ca2+

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dc.contributor.authorBingöl, Haluk
dc.contributor.authorKaykal, Ferhat
dc.contributor.authorAkgemci, Emine Güler
dc.contributor.authorSırıt, Abdulkadir
dc.date.accessioned2020-03-26T17:48:43Z
dc.date.available2020-03-26T17:48:43Z
dc.date.issued2010
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe host-guest complexation reactions between 5,11,17,23-tetra-tert-butyl-25,27-diethoxycarbonylmethoxy-26,28-dimethoxy calix[4] arene ( BDDC4) and alkali and alkaline-earth metal ions were investigated by facilitated ion transfer processes across water/1,2-dichloroethane microinterface by using steady-state cyclic voltammetry and differential pulse voltammetry. The obtained facilitated transfers for Li+, Na+, K+, Rb+ and Ca2+ were evaluated under the different experimental conditions, at the excess concentrations of metal ions with respect to BDDC4 and vice versa. The association constants having 1 : 1 stoichiometry for Li+, Na+, K+ and Rb+ in 1,2-DCE were determined. Also, we demonstrated that BDDC4 can play an important role for the development of highly selective chemical sensor for Ca2+ among alkaline-metal ions in the concentration range of 0.1-1.0 mM in aqueous solution.en_US
dc.description.sponsorshipTUBITAK (Scientific and Technical Research Council of Turkey)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TBAG-107T754]en_US
dc.description.sponsorshipThis work was supported by TUBITAK (Scientific and Technical Research Council of Turkey) under Contract TBAG-107T754. We also thank Prof. Dr. Hubert H. Girault for helpful discussions.en_US
dc.identifier.citationBingöl, H., Kaykal, F., Akgemci, E. G., Sırıt, A., (2010). Facilitated Transfer of Alkali and Alkaline-Earth Metal Ions by a Calix[4]arene Derivative Across Water/1,2-Dichloroethane Microinterface: Amperometric Detection of Ca2+. Electroanalysis, 22(23), 2825-2833. Doi: 10.1002/elan.201000345
dc.identifier.doi10.1002/elan.201000345en_US
dc.identifier.endpage2833en_US
dc.identifier.issn1040-0397en_US
dc.identifier.issn1521-4109en_US
dc.identifier.issue23en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage2825en_US
dc.identifier.urihttps://dx.doi.org/10.1002/elan.201000345
dc.identifier.urihttps://hdl.handle.net/20.500.12395/24929
dc.identifier.volume22en_US
dc.identifier.wosWOS:000285397500010en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorBingöl, Haluk
dc.institutionauthorKaykal, Ferhat
dc.institutionauthorAkgemci, Emine G.
dc.institutionauthorSırıt, Abdulkadir
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofElectroanalysisen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectMicro-ITIESen_US
dc.subjectSteady-state cyclic voltammetryen_US
dc.subjectCalix[4]areneen_US
dc.subjectAlkali ionsen_US
dc.subjectAlkaline-earth ionsen_US
dc.subjectAmperometric sensoren_US
dc.titleFacilitated Transfer of Alkali and Alkaline-Earth Metal Ions by a Calix[4]arene Derivative Across Water/1,2-Dichloroethane Microinterface: Amperometric Detection of Ca2+en_US
dc.typeArticleen_US

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